Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 13, Problem 26P

Quartz, SiO 2 ( s ) , does not spontaneously decompose to siliconand oxygen at 25°C, 1.0 atm in the reaction
SiO 2 ( s ) Si ( s ) + O 2 ( g )

even though the standard entropy change of the reactionis large and positive ( Δ S ° = + 182.02 J K 1 ) . Explain.

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