
Concept explainers
Perform the following arithmetic operations and report the result to the proper number of significant figures: (a) 317.5 mL + 0.675 mL, (b) 47.80 L − 2.075 L, (c) 13.5 g ÷ 45.18 L, (d) 6.25 cm × 1.175 cm, (e) 5.46 × 102g + 4.991 × 103 g.
(a)

Interpretation:
For the given set of calculations, the significant figures and their correct arithmetic operations has to be given.
Concept introduction:
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
To determine: Arithmetic operation is calculated with significant figure.
Answer to Problem 1.5WE
The following arithmetic operation, and report for the resulting the possible number of significant figure is four with answer
Explanation of Solution
Condition for significant figure:
The answer is obtained on the basis of the given number having smallest number (in digits) to the right side of the decimal point
All the non-zero is significant.
There are some conditions for nonzero and significant:
Zero is significant when they appear between non zero digits.
It appears after non zero digit in a number that contain a decimal point.
Zero may or mayn’t be significant if they appear a non-zero to right of the last non zero digit in a number that doesn’t contain a decimal point.
The following arithmetic operation
We can find by adding both the arithmetic value.
Round off the resulting data, we get
For the resulting the possible number of significant figure is four with answer
The answer should contain one digit to the right of the decimal point to match 317.5, which has the fewest digits to the right of the decimal point.
(b)

Interpretation:
For the given set of calculations, the significant figures and their correct arithmetic operations has to be given.
Concept introduction:
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
To determine: Arithmetic operation is calculated with significant figure
Answer to Problem 1.5WE
The following arithmetic operation, and report for the resulting the possible number of significant figure is four with answer
Explanation of Solution
Condition for significant figure:
The answer is obtained on the basis of the given number having smallest number (in digits) to the right side of the decimal point
All the non-zero is significant.
There are some conditions for nonzero and significant:
Zero is significant when they appear between non zero digits.
It appears after non zero digit in a number that contain a decimal point.
Zero may or mayn’t be significant if they appear a non-zero to right of the last non zero digit in a number that doesn’t contain a decimal point.
The following arithmetic operation
We can find by adding both the arithmetic value.
Round off the resulting data, we get
The answer must contain two digits to the right of the decimal point to match 47.80.
(c)

Interpretation:
For the given set of calculations, the significant figures and their correct arithmetic operations has to be given.
Concept introduction:
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
To determine: Arithmetic operation is calculated with significant figure
Answer to Problem 1.5WE
The following arithmetic operation, and report for the resulting the possible number of significant figure is three with answer
Explanation of Solution
Condition for significant figure:
The answer is obtained on the basis of the given number having smallest number (in digits) to the right side of the decimal point
All the non-zero is significant.
There are some conditions for nonzero and significant:
Zero is significant when they appear between non zero digits.
It appears after non zero digit in a number that contain a decimal point.
Zero may or mayn’t be significant if they appear a non-zero to right of the last non zero digit in a number that doesn’t contain a decimal point.
The following arithmetic operation
We can find by adding both the arithmetic value.
Round off the resulting data, we get
The answer will contain three significant figures to match 13.5, which has the few number of significant figures in the calculation.
(d)

Interpretation:
For the given set of calculations, the significant figures and their correct arithmetic operations has to be given.
Concept introduction:
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
To determine: Arithmetic operation is calculated with significant figure
Answer to Problem 1.5WE
The following arithmetic operation, and report for the resulting the possible number of significant figure is three with answer
Explanation of Solution
Condition for significant figure:
The answer is obtained on the basis of the given number having smallest number (in digits) to the right side of the decimal point
All the non-zero is significant.
There are some conditions for nonzero and significant:
Zero is significant when they appear between non zero digits.
It appears after non zero digit in a number that contain a decimal point.
Zero may or mayn’t be significant if they appear a non-zero to right of the last non zero digit in a number that doesn’t contain a decimal point.
The following arithmetic operation
We can find by multiplying both the arithmetic value.
Round off the resulting data, we get
The answer contains three significant figures to match 6.25.
(e)

Interpretation:
For the given set of calculations, the significant figures and their correct arithmetic operations has to be given.
Concept introduction:
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
To determine: Arithmetic operation is calculated with significant figure
Answer to Problem 1.5WE
The following arithmetic operation, and report for the resulting the possible number of significant figure is four with answer
Explanation of Solution
Condition for significant figure:
The answer is obtained on the basis of the given number having smallest number (in digits) to the right side of the decimal point
All the non-zero is significant.
There are some conditions for nonzero and significant:
Zero is significant when they appear between non zero digits.
It appears after non zero digit in a number that contain a decimal point.
Zero may or mayn’t be significant if they appear a non-zero to right of the last non zero digit in a number that doesn’t contain a decimal point.
The following arithmetic operation,
We can find by adding both the arithmetic value.
Round off the resulting data, we get
Firstly, we have to add number to the same power of 10. That is,
Want to see more full solutions like this?
Chapter 1 Solutions
EBK CHEMISTRY: ATOMS FIRST
- The quantum yield of the photochemical decay of HI is 2. Calculating the moles of HI per kJ of radiant energy can be decayed knowing that the energy absorbed per mole of photons is 490 kJ.arrow_forwardThe quantum yield of the photochemical decay of HI is 2. Calculate the number of Einsteins absorbed per mole knowing that the energy absorbed per mole of photons is 490 kJ.arrow_forwardThe quantum yield of the photochemical decay of HI is 2. How many moles of HI per kJ of radiant energy can be decayed knowing that the energy absorbed per mole of photons is 490 kJ.arrow_forward
- If the energy absorbed per mole of photons is 450 kJ, the number of Einsteins absorbed per 1 mole.arrow_forwardWhen propionic aldehyde in vapor form at 200 mmHg and 30°C is irradiated with radiation of wavelength 302 nm, the quantum yield with respect to the formation of CO is 0.54. If the intensity of the incident radiation is 1.5x10-3 W, find the rate of formation of CO.arrow_forwardDraw mechanismarrow_forward
- Does Avogadro's number have units?arrow_forwardExplain why the total E in an Einstein depends on the frequency or wavelength of the light.arrow_forwardIf the dissociation energy of one mole of O2 is 5.17 eV, determine the wavelength that must be used to dissociate it with electromagnetic radiation. Indicate how many Einstein's of this radiation are needed to dissociate 1 liter of O2 at 25°C and 1 atm of pressure.Data: 1 eV = 96485 kJ mol-1; R = 0.082 atm L K-1; c = 2.998x108 m s-1; h = 6.626x10-34 J s; NA = 6.022x 1023 mol-1arrow_forward
- Indicate the number of Einsteins that are equivalent to 550 kJ mol⁻¹ of absorbed energy (wavelength 475 nm).arrow_forwardIndicate the number of einsteins that are equivalent to 550 kJ mol⁻¹ of absorbed energy?arrow_forwardA unit used in photochemistry is the einstein. If 400 kJ mol-1 of energy has been absorbed, how many einsteins is this equivalent to?arrow_forward
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
