The rate of second run has to be compared with the rate of first run. Concept Introduction: The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used. The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L .s) . The variation in concentration of reaction or product over a certain interval of time is called average reaction rate. The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law. Rate law can be determined by the slow step or otherwise called as rate-determining step. To compare the rate of second run wit rate of first run
The rate of second run has to be compared with the rate of first run. Concept Introduction: The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used. The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L .s) . The variation in concentration of reaction or product over a certain interval of time is called average reaction rate. The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law. Rate law can be determined by the slow step or otherwise called as rate-determining step. To compare the rate of second run wit rate of first run
Solution Summary: The author explains that the rate of reaction is the quantity of formation of product, and the amount of reactant used per unit time. The equation that relates the reaction rate to reactants concentrations is called rate law.
Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.
Chapter 13, Problem 13.137QP
Interpretation Introduction
Interpretation:
The rate of second run has to be compared with the rate of first run.
Concept Introduction:
The rate of reaction is the quantity of formation of product or the quantity of reactant used per unit time. The rate of reaction doesn’t depend on the sum of amount of reaction mixture used.
The raise in molar concentration of product of a reaction per unit time or decrease in molarity of reactant per unit time is called rate of reaction and is expressed in units of mol/(L.s).
The variation in concentration of reaction or product over a certain interval of time is called average reaction rate.
The equation that relates the reaction rate to the reactants concentrations that is raised to various powers is called as rate law.
Rate law can be determined by the slow step or otherwise called as rate-determining step.
To compare the rate of second run wit rate of first run
10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 13 Solutions
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