The percent of pyridine ( C 5 H 5 N ) that leads to the formation of pyridium ion ( C 5 H 5 NH + ) in a 0.10 M aqueous solution of pyridine is to be calculated. Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution. The pH of a solution is calculated by the formula, pH = − log [ H + ] At equilibrium, the equilibrium constant expression is expressed by the formula, K b = Concentration of products Concentration of reactants The percent ionization of an acid is calculated by the formula, Percent ionization = Equilibrium concentration of [ OH − ] Initial concentration of the base × 100
The percent of pyridine ( C 5 H 5 N ) that leads to the formation of pyridium ion ( C 5 H 5 NH + ) in a 0.10 M aqueous solution of pyridine is to be calculated. Concept introduction: The pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution. The pH of a solution is calculated by the formula, pH = − log [ H + ] At equilibrium, the equilibrium constant expression is expressed by the formula, K b = Concentration of products Concentration of reactants The percent ionization of an acid is calculated by the formula, Percent ionization = Equilibrium concentration of [ OH − ] Initial concentration of the base × 100
Interpretation: The percent of pyridine
(C5H5N) that leads to the formation of pyridium ion
(C5H5NH+) in a
0.10M aqueous solution of pyridine is to be calculated.
Concept introduction: The
pH of a solution is defined as a figure that expresses the acidity of the alkalinity of a given solution.
The
pH of a solution is calculated by the formula,
pH=−log[H+]
At equilibrium, the equilibrium constant expression is expressed by the formula,
In the laboratory, a general chemistry student measured the pH of a 0.532 M
aqueous solution of hydrofluoric acid to be 1.693.
Use the information she obtained to determine the Ka for this acid.
Ka(experiment) =
Consider the following data on some weak acids and weak bases:
acid
base
Ка
K,
name
formula
name
formula
-4
6.8 x 10
ethylamine C,H,NH, 6.4× 10
-4
hydrofluoric acid
HF
HCH,CO2 1.8 ×x 10
CH;N |1.7× 10
-5
acetic acid
pyridine
1.7 x 10
Use this data to rank the following solutions in order of increasing pH. In other words, select a 'l' next to the solution that will
have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on.
solution
pH
0.1 М KI
choose one
0.1 M NaF
choose one
0.1 М C2HsNHзBr
choose one
0.1 M C5H5NHCI
choose one
What is the pH of a 0.130 M solution of aniline (C₆H₅NH₂, Kb = 4.3 × 10⁻¹⁰)?
Chapter 13 Solutions
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