Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
9th Edition
ISBN: 9781305701021
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 12.SE, Problem 39AP
Carvone is an unsaturated
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The two equations are forms of the Davies equation, used in thermodynamics for
activity coefficients:
ال
log Y₁ = -Az²
- 0,31
log
= Az²
- 0,31
1 + √Ĩ
1 + √√
k
These equations are consistent and imply that
Yi
=
Is this last equation correct?
k
The two equations are forms of the Davies equation, used in thermodynamics for
activity coefficients:
ال
log Y₁ = -Az²
- 0,31
log
= Az²
- 0,31
1 + √Ĩ
1 + √√
k
These equations are consistent and imply that
Yi
=
Is this last equation correct?
k
For the Davies equation, both expressions are correct:
log Y₁ = -Az²
√i
- 0,31
1 +
√
k
log-
= Az
- 0,31
k
1 + √Ĩ
Chapter 12 Solutions
Bundle: Organic Chemistry, 9th, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
Ch. 12.2 - Prob. 1PCh. 12.2 - Two mass spectra are shown in FIGURE 12-8. One...Ch. 12.3 - What are the masses of the charged fragments...Ch. 12.3 - Prob. 4PCh. 12.5 - Prob. 5PCh. 12.5 - Prob. 6PCh. 12.7 - What functional groups might the following...Ch. 12.7 - How might you use IR spectroscopy to distinguish...Ch. 12.8 - Prob. 9PCh. 12.8 - Where might the following compounds have IR...
Ch. 12.8 - Where might the following compound have IR...Ch. 12.SE - Prob. 12VCCh. 12.SE - Show the structures of the fragments you would...Ch. 12.SE - Propose structures for compounds that fit the...Ch. 12.SE - Write molecular formulas for compounds that show...Ch. 12.SE - Camphor, a saturated monoketone from the Asian...Ch. 12.SE - The nitrogen rule of mass spectrometry says that a...Ch. 12.SE - In light of the nitrogen rule mentioned in Problem...Ch. 12.SE - Nicotine is a diamino compound isolated from dried...Ch. 12.SE - The hormone cortisone contains C, H, and O, and...Ch. 12.SE - Halogenated compounds are particularly easy to...Ch. 12.SE - Prob. 22APCh. 12.SE - Propose structures for compounds that fit the...Ch. 12.SE - 2-Methylpentane (C6H14) has the mass spectrum...Ch. 12.SE - Assume that you are in a laboratory carrying out...Ch. 12.SE - What fragments might you expect in the mass...Ch. 12.SE - How might you use IR spectroscopy to distinguish...Ch. 12.SE - Would you expect two enantiomers such as...Ch. 12.SE - Would you expect two diastereomers such as meso-2,...Ch. 12.SE - Propose structures for compounds that meet the...Ch. 12.SE - How could you use infrared spectroscopy to...Ch. 12.SE - Prob. 32APCh. 12.SE - At what approximate positions might the following...Ch. 12.SE - How would you use infrared spectroscopy to...Ch. 12.SE - At what approximate positions might the following...Ch. 12.SE - Assume that you are carrying out the dehydration...Ch. 12.SE - Assume that you are carrying out the base-induced...Ch. 12.SE - Prob. 38APCh. 12.SE - Carvone is an unsaturated ketone responsible for...Ch. 12.SE - Prob. 40APCh. 12.SE - The mass spectrum (a) and the infrared spectrum...Ch. 12.SE - The mass spectrum (a) and the infrared spectrum...Ch. 12.SE - Propose structures for compounds that meet the...Ch. 12.SE - 4-Methyl-2-pentanone and 3-methylpentanal are...Ch. 12.SE - Grignard reagents undergo a general and very...Ch. 12.SE - Ketones undergo a reduction when treated with...Ch. 12.SE - Nitriles, R–=C≡N, undergo a hydrolysis...Ch. 12.SE - The infrared spectrum of the compound with the...Ch. 12.SE - The infrared spectrum of the compound with the...Ch. 12.SE - Prob. 50AP
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- k In Davies' equation log y₁ = log- log y₁ = log | = -Az² + ✓// k A is a constant that always equals 1.02. Correct? - 0,31arrow_forwardIndicate whether the equality is true Yi How is it obtained? k%arrow_forwardIndicate the relationship between the activity coefficient YA and the rate constant of a bimolecular reaction in solution k and the rate constant at infinite dilution ko.arrow_forward
- Describe the saline effect that occurs in solutions.arrow_forwardBriefly explain what the infinite dilution rate constant (k∞) consists of.arrow_forwardThe Davies equation corrects the Debye-Hückel limiting law for calculating the activity coefficient of an electrolyte in solution at relatively high concentrations. Mathematically, it is expressed as: log y₁ = -Az²? 1 + √Ĩ - 0,31) Is the formula correct?arrow_forward
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- plz watch the youtube video (the title of this topic) by roxi H. she explains it step by step but i get the wrong answerarrow_forwardWriting the rate law implied by a simple mechanism To exit full screen, press and hold esc Suppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 →>> O3(9) O2(g) + O(g) k₁ 2 03(g) + O(g) → 202(g) k2 Suppose also k₁ »k2. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. ☐ rate = ☐ Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of K1, K2, and (if necessary) the rate constants k-1 and K-2 for the reverse of the two elementary reactions in the mechanism. k = ☐ 000 18 ローロ Ar OOarrow_forwardDeducing a rate law from the change in concentration over time To exit full screen, press and hold esc A chemistry graduate student is studying the rate of this reaction: H2CO3(aq) → H₂O(aq) +CO₂ (aq) - She fills a reaction vessel with H2CO3 and measures its concentration as the reaction proceeds: time (milliseconds) [H2CO3] 0 0.0500 M 10. 0.0266M 20. 0.0181 M 30. 0.0138M 40. 0.0111 M Use this data to answer the following questions. Write the rate law for this reaction. Calculate the value of the rate constant k. Round your answer to 2 significant digits. Also be sure your answer has the correct unit symbol. rate ☐ x10 k = Х 000 18 Ararrow_forward
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