The strongest bond has to be identified from C=O bond in an ester (1735 cm -1 ) or the C=O bond in a saturated ketone (1715 cm -1 ). Concept introduction: Spectroscopy: It is study of the interaction of matter and electromagnetic radiation, a continuum of different types of electromagnetic radiation each associated with a particular energy range makes up the electromagnetic spectrum. IR frequency (cm -1 ): It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz). Stretch vibrations: It is a vibration occurring along the line of the bond a stretching vibration changes the bond length. Bending vibrations: It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle. Given information: The IR value is given below,

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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Chapter 12.SE, Problem 38AP

Interpretation Introduction

Interpretation:

The strongest bond has to be identified from C=O bond in an ester (1735 cm^-1) or the C=O bond in a saturated ketone (1715 cm^-1).

Concept introduction:

Spectroscopy:

It is study of the interaction of matter and electromagnetic radiation, a continuum of different types of electromagnetic radiation each associated with a particular energy range makes up the electromagnetic spectrum.

IR frequency (cm^-1):

It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Stretch vibrations:

It is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations:

It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Given information:

The IR value is given below,

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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