ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Chapter 12C.2, Problem 7P
Label the protons in each highlighted CH2 group as enantiotopic, diastereotopic, or homotopic.
a. 
b. 
c. 
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Michael Reactions
19.52 Draw the products from the following Michael addition reactions.
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OEt
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EtO
H₂NEt
(d)
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Rank the labeled protons (Ha-Hd) in order of increasing acidity, starting with the least acidic.
НОН НЬ
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Can the target compound at right be efficiently synthesized in good yield from the unsubstituted benzene at left?
?
starting
material
target
If so, draw a synthesis below. If no synthesis using reagents ALEKS recognizes is possible, check the box under the drawing area.
Be sure you follow the standard ALEKS rules for submitting syntheses.
+ More...
Note for advanced students: you may assume that you are using a large excess of benzene as your starting material.
C
:0
T
Add/Remove step
G
Chapter 12C Solutions
ORGANIC CHEMISTRY (LOOSELEAF)
Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2PCh. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9PCh. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P
Ch. 12C.5 - Problem 14.12 Which compound give a NMR spectrum...Ch. 12C.5 - Prob. 14PCh. 12C.6 - Prob. 15PCh. 12C.6 - For each compound give the number of 1H NMR...Ch. 12C.6 - Prob. 17PCh. 12C.7 - Prob. 18PCh. 12C.7 - Problem 14.18 Describe the NMR spectrum of each...Ch. 12C.8 - Problem 14.19 Draw a splitting diagram for in ,...Ch. 12C.8 - Problem 14.20 Identify A and B, isomers of...Ch. 12C.9 - Problem 14.21 How many signals are present in the ...Ch. 12C.9 - Problem 14.22 What protons in alcohol A give rise...Ch. 12C.9 - How many peaks are observed in the NMR signal for...Ch. 12C.10 -
Problem 14.24 Propose a structure for a compound...Ch. 12C - 14.34 (a) How many NMR signals does each of the...Ch. 12C - 14.35 (a) How many NMR signals does each compound...Ch. 12C - Prob. 38PCh. 12C - 14.37 How many NMR signals does each natural...Ch. 12C - Prob. 40PCh. 12C - 14.39 What effect does increasing the operating...Ch. 12C - Prob. 43PCh. 12C - Prob. 44PCh. 12C - Prob. 45PCh. 12C - Prob. 47PCh. 12C - Prob. 48PCh. 12C - 14.48 How many NMR signals does each compound...Ch. 12C - 14.49 Rank the highlighted carbon atoms in each...Ch. 12C - 14.50 Identify the carbon atoms that give rise to...Ch. 12C - 14.62 Reaction of with , followed by treatment...Ch. 12C - Reaction of aldehyde D with amino alcohol E in the...Ch. 12C - 14.64 Propose a structure consistent with each set...
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