ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 12A, Problem 17P
Which compound gives a molecular ion at
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1d. Use Le Chatelier's principle to describe the effect of the following changes on the
position of the Haber-Bosch equilibrium:
N2(g) + 3H2(g)= 2NH3(9) AH = -92kJ
Choose one of the following answers: shift to reactant side, shift to product side or no
change and draw the resulting graph.
I.
Increase the [N2(g)] Effect:
H₂
N₂
NH3
II.
Decrease the volume of the container. Effect:
H₂
N₂2
NH3
f) The unusual molecule [2.2.2] propellane is pictured.
1) Given the bond length and bond angles in the image, what hybridization scheme
best describes the carbons marked by the askerisks?
2) What types of orbitals are used in the bond between the two carbons marked by
the askerisks?
3) How does this bond compare to an ordinary carbon-carbon bond (which is usually
1.54 Å long)?
CH2 1.60Å
H₂C *
H₂C
CH2
C
H2C
*
C
Of
H₂
120°
e) Determine the hybridization and geometry around the indicated carbon atoms.
H3C
CH3
B
HC
CH2
A
C
C
C
CH3
Chapter 12A Solutions
ORGANIC CHEMISTRY-ACCESS
Ch. 12A.1 - What is the mass of the molecular ion formed from...Ch. 12A.1 - Prob. 3PCh. 12A.2 - Prob. 6PCh. 12A.2 - What molecular ions would you expect for the...Ch. 12A.3 - The mass spectrum of 2,3-dimethylpentane also...Ch. 12A.3 - The base peak in the mass spectrum of 2, 2,...Ch. 12A - Problem-13.24 The mass spectrum of the following...Ch. 12A - Prob. 16PCh. 12A - Which compound gives a molecular ion at m/z= 122,...Ch. 12A - Propose two molecular formulas for each molecular...
Ch. 12A - Propose four possible structures for a hydrocarbon...Ch. 12A - Problem-13.29 What is the molecular formula for...Ch. 12A - Problem-13.30 Propose a molecular formula for rose...Ch. 12A - 13.31 Match each structure to its mass spectrum
Ch. 12A - 13.32 Propose two possible structures for a...
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