
Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Chapter 12.5, Problem 59PP
Interpretation Introduction
Interpretation:
Initial concentration of glucose solution in millilitres should be identified.
Concept introduction:
The amount of the solute in the new diluted solution is equal to the amount of the solute in the solution before dilution. i.e.
concentrated = diluted
solution solution
This is the dilution expression.
Given:
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The following is a total synthesis of the pheromone of the western pine beetle. Such
syntheses are interesting both because of the organic chemistry, and because of the possibility of
using species specific insecticides, rather than broad band insecticides. Provide the reagents for
each step. There is some chemistry from our most recent chapter in this synthesis, but other
steps are review from earlier chapters. (8 points)
COOEt
COOEt
A
C
COOEt
COOEt
COOH
B
OH
OTS
CN
D
E
See the last homework set
F
for assistance on this one.
H+, H₂O
G
OH
OH
The last step is just nucleophilic addition reactions, taking the
ketone to an acetal, intramolecularly. But
it is hard to visualize the three dimensional shape as
it occurs.
Frontalin, pheromone of the western pine beetle
For the reaction below:
1. Draw all reasonable elimination products to the right of the arrow.
2. In the box below the reaction, redraw any product you expect to be a major product.
C
Major Product:
Check
+
◎
+
X
ง
©
Cl
I
F2
80
F3
I
σ
F4
I
F5
NaOH
Click and
drawing
F6
A
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Chapter 12 Solutions
Basic Chemistry
Ch. 12.1 - Identify the solute and the solvent in each...Ch. 12.1 - Identify the solute and the solvent in each...Ch. 12.1 - Describe the formation of an aqueous KI solution,...Ch. 12.1 - Prob. 4PPCh. 12.1 - Water is a polar solvent and carbon tetrachloride...Ch. 12.1 - Water is a polar solvent and hexane (C6H14) is a...Ch. 12.2 - KF is a strong electrolyte, and HF is a weak...Ch. 12.2 - Prob. 8PPCh. 12.2 - Prob. 9PPCh. 12.2 - Prob. 10PP
Ch. 12.2 - Indicate whether aqueous solutions of each of the...Ch. 12.2 - Prob. 12PPCh. 12.2 - Classify the solute represented in each of the...Ch. 12.2 - Prob. 14PPCh. 12.3 - Prob. 15PPCh. 12.3 - State whether each of the following refers to a...Ch. 12.3 - Prob. 17PPCh. 12.3 - Prob. 18PPCh. 12.3 - A solution containing 80.g of KCl in 200.g of H2O...Ch. 12.3 - A solution containing 80.g of NaNO3 in 75g of H2O...Ch. 12.3 - Prob. 21PPCh. 12.3 - Prob. 22PPCh. 12.3 - Prob. 23PPCh. 12.3 - Prob. 24PPCh. 12.3 - Prob. 25PPCh. 12.3 - Determine whether a solid forms when solutions...Ch. 12.4 - What is the difference between a 5.00(m/m) glucose...Ch. 12.4 - What is the difference between a 10.0 (v/v)...Ch. 12.4 - Calculate the mass percent (m/m) for the solute in...Ch. 12.4 - Calculate the mass percent (m/m) for the solute in...Ch. 12.4 - Calculate the mass/volume percent (m/v) for the...Ch. 12.4 - Calculate the mass/volume percent (m/v) for the...Ch. 12.4 - Prob. 33PPCh. 12.4 - Calculate the grams or milliliters of solute...Ch. 12.4 - Prob. 35PPCh. 12.4 - Prob. 36PPCh. 12.4 - Prob. 37PPCh. 12.4 - For each of the following solutions, calculate...Ch. 12.4 - Prob. 39PPCh. 12.4 - Prob. 40PPCh. 12.4 - Prob. 41PPCh. 12.4 - Prob. 42PPCh. 12.4 - For each of the following solutions, calculate...Ch. 12.4 - For each of the following solutions, calculate...Ch. 12.4 - Calculate the volume, in milliliters, for each of...Ch. 12.4 - Prob. 46PPCh. 12.4 - Prob. 47PPCh. 12.4 - Prob. 48PPCh. 12.4 - A patient needs 100.g of glucose in the next 12h ....Ch. 12.4 - A patient received 2.0g of NaCl in 8h . How many...Ch. 12.5 - Prob. 51PPCh. 12.5 - A can of frozen lemonade calls for the addition of...Ch. 12.5 - Prob. 53PPCh. 12.5 - Prob. 54PPCh. 12.5 - Determine the final volume, in milliliters, of...Ch. 12.5 - Determine the final volume, in milliliters, of...Ch. 12.5 - Prob. 57PPCh. 12.5 - Prob. 58PPCh. 12.5 - Prob. 59PPCh. 12.5 - Prob. 60PPCh. 12.6 - Prob. 61PPCh. 12.6 - Prob. 62PPCh. 12.6 - Answer the following for the reaction:...Ch. 12.6 - Prob. 64PPCh. 12.6 - Prob. 65PPCh. 12.6 - Answer the following for the reaction:...Ch. 12.7 - Prob. 67PPCh. 12.7 - Prob. 68PPCh. 12.7 - Prob. 69PPCh. 12.7 - Prob. 70PPCh. 12.7 - Prob. 71PPCh. 12.7 - Prob. 72PPCh. 12.7 - Prob. 73PPCh. 12.7 - In each pair, identify the solution that will have...Ch. 12.8 - A 10(m/v) starch solution is separated from a...Ch. 12.8 - A 0.1(m/v) albumin solution is separated from a...Ch. 12.8 - Indicate the compartment (A or B) that will...Ch. 12.8 - Prob. 78PPCh. 12.8 - Prob. 79PPCh. 12.8 - Will a red blood cell undergo crenation,...Ch. 12.8 - Prob. 81PPCh. 12.8 - Each of the following mixtures is placed in a...Ch. 12.8 - Prob. 83PPCh. 12.8 - Prob. 84PPCh. 12.8 - Prob. 85PPCh. 12.8 - Prob. 86PPCh. 12 - The chapter sections to review are shown in...Ch. 12 - Prob. 88UTCCh. 12 - The chapter sections to review are shown in...Ch. 12 - Prob. 90UTCCh. 12 - Prob. 91UTCCh. 12 - Prob. 92UTCCh. 12 - Prob. 93UTCCh. 12 - Prob. 94UTCCh. 12 - Prob. 95UTCCh. 12 - Prob. 96UTCCh. 12 - Why does iodine dissolve in hexane, but not in...Ch. 12 - How do temperature and pressure affect the...Ch. 12 - Prob. 99APPCh. 12 - Prob. 100APPCh. 12 - Prob. 101APPCh. 12 - Prob. 102APPCh. 12 - Prob. 103APPCh. 12 - Write the net ionic equation to show the formation...Ch. 12 - Prob. 105APPCh. 12 - Prob. 106APPCh. 12 - Calculate the mass percent (m/m) of a solution...Ch. 12 - Calculate the mass percent (m/m) of a solution...Ch. 12 - How many milliliters of a 12 (v/v) propyl alcohol...Ch. 12 - Prob. 110APPCh. 12 - Prob. 111APPCh. 12 - Prob. 112APPCh. 12 - Prob. 113APPCh. 12 - Prob. 114APPCh. 12 - Prob. 115APPCh. 12 - Prob. 116APPCh. 12 - Prob. 117APPCh. 12 - How many liters of a 4.00MNaCl solution will...Ch. 12 - How many grams of solute are in each of the...Ch. 12 - Prob. 120APPCh. 12 - Prob. 121APPCh. 12 - Prob. 122APPCh. 12 - Prob. 123APPCh. 12 - Prob. 124APPCh. 12 - Prob. 125APPCh. 12 - Prob. 126APPCh. 12 - Prob. 127APPCh. 12 - Prob. 128APPCh. 12 - Prob. 129APPCh. 12 - Prob. 130APPCh. 12 - Prob. 131APPCh. 12 - Prob. 132APPCh. 12 - Prob. 133CPCh. 12 - Prob. 134CPCh. 12 - Prob. 135CPCh. 12 - Prob. 136CPCh. 12 - Prob. 137CPCh. 12 - Prob. 138CPCh. 12 - Prob. 139CPCh. 12 - Prob. 140CPCh. 12 - Prob. 141CPCh. 12 - Prob. 142CPCh. 12 - Prob. 143CPCh. 12 - Prob. 144CPCh. 12 - Prob. 145CPCh. 12 - Prob. 146CPCh. 12 - The following problems are related to the topics...Ch. 12 - Prob. 148CP
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