(a)
Interpretation: The synthetic route for the preparation of given transformations should be determined.
Concept Introduction:
Addition Reaction: It is defined as
Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.
Anti-Markovnikov’s Addition Rule: The unsymmetrical
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.
Ozonolysis Reaction: It is an oxidative reaction which is used to oxidise the carbon-carbon double and triple bond.
Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.
To identify: The synthetic route to accomplish the given transformation.
Draw the structure for given substrate and product
(b)
Interpretation: The synthetic route for the preparation of given transformations should be determined.
Concept Introduction:
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.
Anti-Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the less substitution position of carbon-carbon double bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.
Ozonolysis Reaction: It is an oxidative reaction which is used to oxidise the carbon-carbon double and triple bond.
Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.
To identify: The synthetic route to accomplish the given transformation.
Draw the structure for given substrate and product.
(c)
Interpretation: The synthetic route for the preparation of given transformations should be determined.
Concept Introduction:
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.
Anti-Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the less substitution position of carbon-carbon double bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.
Ozonolysis Reaction: It is an oxidative reaction which is used to oxidise the carbon-carbon double and triple bond.
Oxidation Reaction: It involves loss of electrons, addition of oxygen atoms or removal of hydrogen atoms.
To identify: The synthetic route to accomplish the given transformation.
Draw the structure for given substrate and product.
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Chapter 12 Solutions
ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
- Can I please get help with this question. All required information should be in data table.arrow_forwardesc For the reaction below: 1. Draw all reasonable elimination products to the right of the arrow. 2. In the box below the reaction, redraw any product you expect to be a major product. Major Product: Explanation Check C ☐ + X NaOH Br F1 F2 80 F3 F4 F5 F6 1 ! @ 2 3 $ 4 % 5 Q W LU E S D A F7 * C Click and dr drawing a 2025 McGraw Hill LLC. All Rights Reserv ►II F8 4 F9 6 7 8 9 R T Y U LL F G H Jarrow_forwardCalculate equilibrium concentrations for the following reaction:N2 (g) + O2 (g) ⇋ 2 NO (g) Kc = 0.10 at 2273K initially [N2] = 0.200M; [O2] = 0.200arrow_forward
- For each scenario below, select the color of the solution using the indicator thymol blue during the titration. When you first add indicator to your Na2CO3solution, the solution is basic (pH ~10), and the color is ["", "", "", "", ""] . At the equivalence point for the titration, the moles of added HCl are equal to the moles of Na2CO3. One drop (or less!) past this is called the endpoint. The added HCl begins to titrate the thymol blue indicator itself. At the endpoint, the indicator color is ["", "", "", "", ""] . When you weren't paying attention and added too much HCl (~12 mL extra), the color is ["", "", "", "", ""] . When you really weren't paying attention and reached the second equivalence point of Na2CO3, the color isarrow_forwardThe following reaction is run in which the initial conditions include only methane (CH4) at a concentration of0.115 M. Once equilibrium was established, the concentration of acetylene (C2H2) was measured to be 0.035M. What is the value of the equilibrium constant, K?2 CH4 (g) ⇋ C2H2 (g) + 3 H2 (g)arrow_forwardCalculate the equilibrium concentration of carbon dioxide for the following reaction:2 COF2 (g) ⇋ CF4 (g) + CO2 (g) Kc = 2.00 at 10.00 °C. at equilibrium [COF2] = 0.255M; [CF4] = 0.118Marrow_forward
- In a benzene derivative that has -CH2CH3, indicate how it can be substituted by -COOH.arrow_forwardIn a sulfonated derivative of benzene, indicate how -SO3H can be eliminated.arrow_forwardWhat is the equilibrium expression (law of mass action) for the following reaction:CO2 (g) + H2O (l) ⇋ H+ (aq) + HCO3- (aq)arrow_forward
- Indicate the compound resulting from adding NaOH cyclopentane-CH2-CHO.arrow_forwardUse the provided information to calculate Kc for the following reaction at 550 °C: H2(g) + CO2(g) ⇌ CO(g) + H2O(g) Kc = ?CoO(s) + CO(g) ⇌ Co(s) + CO2(g) Kc1 = 490CoO(s) + H2(g) ⇌ Co(s) + H2O(g) Kc2 = 67arrow_forwardCalculate Kc for the reaction: I2 (g) ⇋ 2 I (g) Kp = 6.26 x 10-22 at 298Karrow_forward
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