ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Chapter 12.2, Problem 5ATS
Interpretation Introduction

Interpretation: The reagents used in the given conversion should be identified.

Concept Introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Elimination Reaction: It is just reverse reaction of addition where substituent from the given molecule is removed via E1 (the reaction depends only on the substrate involved in the reaction) or E2 (the reaction depends on both of the substituents in the reaction) mechanism.

Anti-Markovnikov’s Addition Rule: The unsymmetrical alkene in a chemical compound reacts with hydrogen halide in a way, where halide ions attacks and bond to the less substitution position of carbon-carbon double bond.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

To identify: The reagents used in the given conversion.

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21. Zn Cl₂→ ZnCl2 22. ZnCO3 ZnO CO₂ 23. Mg + Sg MgS 24. Fe + Cl₂ FeCl3 25. Ag + S8 Ag₂S 26. K S8 K₂S 27. Al HCI AlCl3 H2 28. Mg H3PO4 Mg3(PO4)2 + H₂ 29. Cu + AgNO3 Cu(NO3)2 + Ag 30. Al + Pb(NO3)2 Pb + Al(NO3)3 31. Zn + Sn(NO3)4 Zn(NO3)2 Sn 32. Cl2 + All 3 AlCl3 _ 12 33. Br2 + Cul CuBr 12 34. KBr + Pb(NO3)2 KNO3 PbBr2 These next ones have an element shared between two different compounds. The Total amount in the Reactatnt still needs to equal the total amount in the product. 35.H₂O2 ← H₂O + 0₂ 36. C₂Ho CO2 + H₂O 37. Zn + HCI → ZnCl+ H₂ 38. NH3 + _HCl → NH.C 39. Mg(OH)2 + H3PO4 → H₂O+ Mg3(PO4)2 40. NHẠOH + FeCl3 NH4Cl + Fe(OH)3
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