It is given that, the instability of long chains of silicon atoms play a very important role in its decomposition. The reason of the fact that, the similar mechanism not be expected to play a very important role in the decomposition of long chains of carbon atoms is to be stated. Concept introduction: The linkage of atoms through covalent bond to form longer chains and structures is known as catenation. To determine : The reason of the fact that, the similar mechanism (as of silicon) not be expected to play a very important role in the decomposition of long chains of carbon atoms.
It is given that, the instability of long chains of silicon atoms play a very important role in its decomposition. The reason of the fact that, the similar mechanism not be expected to play a very important role in the decomposition of long chains of carbon atoms is to be stated. Concept introduction: The linkage of atoms through covalent bond to form longer chains and structures is known as catenation. To determine : The reason of the fact that, the similar mechanism (as of silicon) not be expected to play a very important role in the decomposition of long chains of carbon atoms.
Solution Summary: The author explains that the instability of long chains of silicon atoms plays a very important role in its decomposition.
Interpretation: It is given that, the instability of long chains of silicon atoms play a very important role in its decomposition. The reason of the fact that, the similar mechanism not be expected to play a very important role in the decomposition of long chains of carbon atoms is to be stated.
Concept introduction: The linkage of atoms through covalent bond to form longer chains and structures is known as catenation.
To determine: The reason of the fact that, the similar mechanism (as of silicon) not be expected to play a very important role in the decomposition of long chains of carbon atoms.
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell