EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
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Chapter 12, Problem 70E
Interpretation Introduction
To determine:
Heat required to convert 1 mol of steam at 145° to ice at −50°.
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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The acid-base chemistry of both EDTA and EBT are important to ensuring that the reactions proceed as desired, thus the pH is controlled using a buffer. What percent of the EBT indicator will be in the desired HIn2- state at pH = 10.5. pKa1 = 6.2 and pKa2 = 11.6 of EBT
Chapter 12 Solutions
EBK CHEMISTRY
Ch. 12 - Prob. 1SAQCh. 12 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 12 - Taking intermolecular forces into account, which...Ch. 12 - What substance experiences dipole-dipole forces?...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Determine the amount of heat (in kJ) required to...Ch. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 11SAQCh. 12 - Why do ethanol and dimethyl ether have such...Ch. 12 - Why are intermolecular forces important?Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Which factors cause transitions between the solid...Ch. 12 - Describe the relationship between the state of a...Ch. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - What is the ion-dipole force? Why is it important?Ch. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - What is capillary action? How does it depend on...Ch. 12 - Explain what happens during the processes of...Ch. 12 - Why is vaporization endothermic? Why is...Ch. 12 - Prob. 20ECh. 12 - What is the heat of vaporization for a liquid, and...Ch. 12 - Explain the process of dynamic equilibrium. How is...Ch. 12 - What happens to a system in dynamic equilibrium...Ch. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Examine the heating curve for water in section...Ch. 12 - What is a phase diagram? What is the significance...Ch. 12 - Draw a generic phase diagram and label its...Ch. 12 - Prob. 35ECh. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Determine the kinds of intermolecular forces that...Ch. 12 - Prob. 38ECh. 12 - Arrange these compounds in order of increasing...Ch. 12 - Prob. 40ECh. 12 - Pick the compound with the highest boiling point...Ch. 12 - Pick the compound with the highest boiling point...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Water (a) “wets” some surfaces and beads up on...Ch. 12 - The structures of two isomers of heptanes are...Ch. 12 - Prob. 50ECh. 12 - Water in a glass tube that contains grease or oil...Ch. 12 - When a thin glass tube is put into water, the...Ch. 12 - Which evaporates more quickly: 55 mL of water in a...Ch. 12 - Prob. 54ECh. 12 - Spilling room temperature water over your skin on...Ch. 12 - Prob. 56ECh. 12 - The human body obtains 915 kJ of energy from a...Ch. 12 - Prob. 58ECh. 12 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - How much energy is released when 65.8 g of water...Ch. 12 - Prob. 66ECh. 12 - An 8.5 g ice cube is placed into 255 g of water....Ch. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - The high-pressure phase diagram of ice is shown...Ch. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - How is the density of solid water compared to that...Ch. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Four ice cubes at exactly 00C with a total mass of...Ch. 12 - Prob. 86ECh. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Draw a heating curve (such as the one in Figure...Ch. 12 - Prob. 89ECh. 12 - A sealed flask contains 0.55 g of water at 280C....Ch. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Given that the heat of fusion of water is —6.02...Ch. 12 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 12 - Prob. 96ECh. 12 - Prob. 97E
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