Based on the given ρ values, the series of reactants in which there is a greater degree of C-H bond breaking at the transition state is to be determined. Concept introduction: A positive value of reaction constant indicates that the transition state has more negative charge than the reactant. A negative value of reaction constant indicates that the transition state has more positive charge than the reactant. E2 elimination reaction is a one-step reaction. The breaking of C-H bond, formation of a new pi bond, and the departure of the leaving group occur in the single step.

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Chapter 12, Problem 66DSP

Interpretation Introduction

Interpretation:

Based on the given ρ values, the series of reactants in which there is a greater degree of C-H bond breaking at the transition state is to be determined.

Concept introduction:

A positive value of reaction constant indicates that the transition state has more negative charge than the reactant.

A negative value of reaction constant indicates that the transition state has more positive charge than the reactant.

E2 elimination reaction is a one-step reaction.

The breaking of C-H bond, formation of a new pi bond, and the departure of the leaving group occur in the single step.

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