ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
ORGANIC CHEMISTRY,SOLN.MAN.+...-ACCESS
4th Edition
ISBN: 9781119659471
Author: Klein
Publisher: WILEY
Question
Book Icon
Chapter 12, Problem 65IP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (b)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(d)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (e)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (f)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(g)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(h)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(i)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(j)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(k)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (l)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (m)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (n)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(o)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

 (p)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(q)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(r)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

(s)

Interpretation Introduction

Interpretation:

The synthesis of the given product transformation should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using Pbr3 which provides corresponding brominated products.

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Alcohols treated with any metals or base which provides alkoxide.

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols

Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.

Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.

Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

Kucherov Reaction:

Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.

Blurred answer
Students have asked these similar questions
Predict the product formed when the compound shown below undergoes a reaction with MCPBA in CH2Cl2. MCPBA is meta-chloroperoxybenzoic acid.
k https://app.aktiv.com STARTING AMOUNT 6 58°F Clear + F1 X Dimensional Analysis - Aktiv Chemistry Your Aktiv Learning trial expires on 02/25/25 at 02:14 PM Question 19 of 22 Polyethylene terephthalate (PET) is used in plastic water bottles. A water bottle has a mass of 14.0 grams. Given a density of 1.38 g/cm³, what is the volume of the plastic used to make the water bottle in cm³ ? ADD FACTOR ANSWER RESET ว 100 14.0 0.01 10.1 1000 0.099 1.38 0.001 Q Search F5 -O+ F6 F7 + F3 F2 W E S4 ST #3 F4 % 5 Y R S & 7 cm³ g/cm³ g ם F8 * 00 8 F9 P ل DOD S F10 F11 F12 Insert D F G H J K + 11
A doctor gives a patient 10 Ci of beta radiation. How many betaparticles would the patient receive in 1 minute? (1 Ci = 3.7 x 1010d/s)
Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY