The substance among the given pair that has the lower boiling point is to be identified. Concept introduction: Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows: 1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule. 2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule. 3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole. 4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule. 5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule. 6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces. The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm . The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows: dispersion forces < dipole − dipole forces < hydrogen bonds < ion − dipole forces

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Answer 1

Question

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Answer 2

Question

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Answer 3

Question

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

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Check out a sample textbook solution

See solution

Answer 5

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 6

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 7

Chapter 12, Problem 12.53P

(a)

Interpretation Introduction

Interpretation:

The substance among the given pair that has the lower boiling point is to be identified.

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 8

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

NaBr or PBr3

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

An ionic bond is formed by the interaction of a metal with a non-metal. When a metal element interacts with a non-metal, the metal loses electron/electrons. The electrons lost are gained by the nonmetal. The metal turns into a cation whereas the non-metal turns into an anion. The electrostatic force of attraction between the cation and the anion leads to the formation of an ionic bond between the two. The constituents in an ionic compound are ions.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 11

(c)

Interpretation Introduction

Interpretation:

The substance among the following pair that has the lower boiling point is to be identified.

H2O or HBr

Concept introduction:

Intermolecular forces operate between the molecules so changes with change in the phase and effects with physical properties of the substance. In intermolecular forces, the bond is formed between two molecules with partial charges that are present relatively far away from each other. The types of intermolecular forces are as follows:

1. Ion-dipole: Ion-dipole forces are the attractive forces that exist between an ion and a polar molecule.

2. Hydrogen bond: Hydrogen bonding is the attractive forces that exist between the molecule with a hydrogen atom bonded to an electronegative atom like fluorine, nitrogen, and oxygen of one molecule and an electronegative atom of another molecule.

3. Dipole-dipole: Dipole-dipole is the attractive forces that exist between two polar molecules that have a permanent dipole.

4. Ion-induced dipole: Ion-induced dipole is the attractive forces that exist between the ion and a nonpolar molecule.

5. Dipole-induced dipole: Dipole-induced dipole is the attractive forces that exist between a polar and a nonpolar molecule.

6. Dispersion forces: In dispersion forces, a temporary dipole is generated on one molecule that further induces a temporary dipole on the molecule adjacent to it. The temporary dipole results in the attraction between opposite charges and dispersion forces exist in the molecule. All the atoms and molecules exhibit dispersion forces.

The boiling point of the liquid is defined as the temperature at which the liquid and gas are in equilibrium and the pressure is 1 atm. The boiling point is directly related to the strength of intermolecular forces. More is the strength of intermolecular forces more will be the boiling point of the compound. The increasing order of strength is as follows:

dispersion forces<dipole−dipole forces<hydrogen bonds<ion−dipole forces

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 12.2 - Prob. 12.1AFP Ch. 12.2 - Prob. 12.1BFP Ch. 12.2 - Prob. 12.2AFP Ch. 12.2 - Prob. 12.2BFP Ch. 12.2 - Prob. 12.3AFP Ch. 12.2 - Prob. 12.3BFP Ch. 12.3 - Prob. 12.4AFP Ch. 12.3 - Prob. 12.4BFP Ch. 12.3 - Prob. 12.5AFP Ch. 12.3 - Prob. 12.5BFP

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