CHEMISTRY-W/MASTERING CHEMISTRY ACCESS
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ISBN: 9780135205068
Author: Robinson
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Chapter 12, Problem 12.4A
The density of a sample of metal "as measured to be 22.67 g/cm3. An X-ray diffraction experiment measures the edge of a face-centered cubic cell as 383.3 pm. Calculate the
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that NH3 is a weak base.
acids: ☐
1.8 mol of HCl is added to
1.0 L of a 1.0M NH3
bases: ☐
solution.
other: ☐
0.18 mol of HNO3 is added
to 1.0 L of a solution that is
1.4M in both NH3 and
NH₁Br.
acids:
bases: ☐
other: ☐
0,0,...
?
000
18
Ar
B
1
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
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18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
18
Ar
Chapter 12 Solutions
CHEMISTRY-W/MASTERING CHEMISTRY ACCESS
Ch. 12 - Calcium metal crystallizes in a cubic...Ch. 12 - Polonium metal crystallizes in a simple cubic...Ch. 12 - Polonium metal crystallizes in a simple cubic...Ch. 12 - The density of a sample of metal "as measured to...Ch. 12 - Zinc sulfide crystallizes in the following cubic...Ch. 12 - Prob. 12.6ACh. 12 - Prob. 12.7PCh. 12 - Prob. 12.8ACh. 12 - Prob. 12.9PCh. 12 - Prob. 12.10A
Ch. 12 - Prob. 12.11PCh. 12 - Prob. 12.12ACh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14PCh. 12 - Prob. 12.15PCh. 12 - Prob. 12.16PCh. 12 - Prob. 12.17PCh. 12 - Identify each of the following kinds of packingCh. 12 - Prob. 12.19CPCh. 12 - Titanium oxide crystallizes in the following cubic...Ch. 12 - Prob. 12.21CPCh. 12 - Prob. 12.22CPCh. 12 - Prob. 12.23CPCh. 12 - Prob. 12.24CPCh. 12 - Prob. 12.25CPCh. 12 - Prob. 12.26SPCh. 12 - Prob. 12.27SPCh. 12 - Prob. 12.28SPCh. 12 - Prob. 12.29SPCh. 12 - Prob. 12.30SPCh. 12 - Prob. 12.31SPCh. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Diffraction of X rays with =154.2 pm at an angle...Ch. 12 - Which of the four kinds of packing used by metals...Ch. 12 - What is a unit cell? How many atoms are in one...Ch. 12 - Copper crystallizes in a face-centered cubic unit...Ch. 12 - Lead crystallizes in a cubic unit cell with anedge...Ch. 12 - Prob. 12.38SPCh. 12 - Tungsten crystallizes in a body-centered cubic...Ch. 12 - Prob. 12.40SPCh. 12 - Prob. 12.41SPCh. 12 - Titanium metal has a density of and an atomic...Ch. 12 - Calcium metal has a density of 1.55 g/cm3 and...Ch. 12 - The atomic radius of Pb is 175 pm, and the density...Ch. 12 - The density of a sample of metal was measured to...Ch. 12 - If a protein can be induced to crystallize, its...Ch. 12 - The molecular structure of a scorpion toxin, a...Ch. 12 - Iron crystallizes in a body-centered cubic unit...Ch. 12 - Silver metal crystallizes in a face-centered cubic...Ch. 12 - Sodium hydride, NaH, crystallizes in a...Ch. 12 - Cesium chloride crystallizers in a cubic unit cell...Ch. 12 - If the edge length of an NaH unit cell is 488 pm,...Ch. 12 - The edge length of a CsCI unit cell (Problem...Ch. 12 - Silicon carbide, SiC, is a covalent network solid...Ch. 12 - Prob. 12.55SPCh. 12 - Prob. 12.56SPCh. 12 - Prob. 12.57SPCh. 12 - Prob. 12.58SPCh. 12 - Prob. 12.59SPCh. 12 - Prob. 12.60SPCh. 12 - Prob. 12.61SPCh. 12 - Prob. 12.62SPCh. 12 - Prob. 12.63SPCh. 12 - Prob. 12.64SPCh. 12 - Prob. 12.65SPCh. 12 - Prob. 12.66SPCh. 12 - Prob. 12.67SPCh. 12 - Prob. 12.68SPCh. 12 - Prob. 12.69SPCh. 12 - Prob. 12.70SPCh. 12 - Prob. 12.71SPCh. 12 - Prob. 12.72SPCh. 12 - Prob. 12.73SPCh. 12 - Prob. 12.74SPCh. 12 - Prob. 12.75SPCh. 12 - Prob. 12.76SPCh. 12 - Prob. 12.77SPCh. 12 - Prob. 12.78SPCh. 12 - Prob. 12.79SPCh. 12 - Prob. 12.80SPCh. 12 - Prob. 12.81SPCh. 12 - Prob. 12.82SPCh. 12 - Prob. 12.83SPCh. 12 - Prob. 12.84SPCh. 12 - Prob. 12.85SPCh. 12 - Prob. 12.86SPCh. 12 - Prob. 12.87SPCh. 12 - Prob. 12.88SPCh. 12 - Prob. 12.89SPCh. 12 - Prob. 12.90SPCh. 12 - Prob. 12.91SPCh. 12 - Prob. 12.92SPCh. 12 - Prob. 12.93SPCh. 12 - Prob. 12.94SPCh. 12 - Prob. 12.95SPCh. 12 - Prob. 12.96SPCh. 12 - Prob. 12.97SPCh. 12 - Prob. 12.98SPCh. 12 - Prob. 12.99SPCh. 12 - Prob. 12.100SPCh. 12 - Prob. 12.101SPCh. 12 - A photovoltaic cell contains a p-n junction that...Ch. 12 - Prob. 12.103SPCh. 12 - Prob. 12.104SPCh. 12 - Prob. 12.105SPCh. 12 - Prob. 12.106SPCh. 12 - Prob. 12.107SPCh. 12 - Prob. 12.108SPCh. 12 - Prob. 12.109SPCh. 12 - Prob. 12.110SPCh. 12 - Prob. 12.111SPCh. 12 - Prob. 12.112SPCh. 12 - Prob. 12.113SPCh. 12 - Prob. 12.114SPCh. 12 - Prob. 12.115SPCh. 12 - Prob. 12.116SPCh. 12 - Prob. 12.117SPCh. 12 - Prob. 12.118SPCh. 12 - Prob. 12.119SPCh. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - Prob. 12.125SPCh. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SPCh. 12 - Prob. 12.130SPCh. 12 - Prob. 12.131SPCh. 12 - Prob. 12.132SPCh. 12 - Prob. 12.133SPCh. 12 - Prob. 12.134MPCh. 12 - Prob. 12.135MPCh. 12 - Prob. 12.136MPCh. 12 - Prob. 12.137MPCh. 12 - Assume that 1588 g of an alkali metal undergoes...Ch. 12 - Prob. 12.139MPCh. 12 - Prob. 12.140MPCh. 12 - Prob. 12.141MPCh. 12 - Prob. 12.142MPCh. 12 - Prob. 12.143MPCh. 12 - Prob. 12.144MP
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