Principles of Chemistry: A Molecular Approach, Books a la Carte Plus Mastering Chemistry with eText - Access Card Package (3rd Edition)
3rd Edition
ISBN: 9780133902419
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 12, Problem 12.1P
Interpretation Introduction
Interpretation:
The compounds soluble in hexane are to be identified.
Concept introduction: The polarity of solute and solvent determines the solubility of solution. Solute and solvent of same polarity are soluble with each other and insoluble if polarity is different.
To determine: The compounds soluble in hexane.
Expert Solution & Answer
Answer to Problem 12.1P
Solution:
- Water is not soluble in hexane.
- Propane is soluble in hexane.
- Ammonia is not soluble in hexane.
- Hydrogen chloride is not soluble in hexane.
(a)
Explanation of Solution
The molecular structure of water consists of two hydrogen atoms bonded with one oxygen atom. The oxygen atom being electronegative element withdraw electrons from hydrogen atoms and become partial negatively charged.
However, hexane is a non-polar molecule and it does not solubilize polar compounds. Therefore, Water is not soluble in hexane.
(b)
Propane consists of three carbon atoms attached to each other in chain. The dipole moment of same elements bonded with each other is zero. Hence propane is a non-polar molecule and can solubilize in non-polar hexane.
(c)
The three hydrogen atoms in ammonia are bonded with nitrogen atom having one pair of electrons. The structure of the molecule is not symmetrical and nitrogen withdraws electrons towards itself.
Hence, ammonia is a polar molecule. Therefore, it is not soluble in hexane.
(d)
The electronegativity of chlorine in
However, hexane is a non-polar molecule and it does not solubilize polar compounds. Therefore, hydrogen chloride is not soluble in hexane.
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Chapter 12 Solutions
Principles of Chemistry: A Molecular Approach, Books a la Carte Plus Mastering Chemistry with eText - Access Card Package (3rd Edition)
Ch. 12 - Prob. 12.1PCh. 12 - Prob. 12.2PCh. 12 - For Practice 12.3 What mass of sucrose...Ch. 12 - Prob. 12.3MPCh. 12 - Prob. 12.4PCh. 12 - Prob. 12.5PCh. 12 - Prob. 12.5MPCh. 12 - Prob. 12.6PCh. 12 - Prob. 12.6MPCh. 12 - Prob. 12.7P
Ch. 12 - Prob. 12.8PCh. 12 - Prob. 12.9PCh. 12 - Prob. 12.10PCh. 12 - Prob. 12.11PCh. 12 - Prob. 12.12PCh. 12 - Prob. 1SAQCh. 12 - Prob. 2SAQCh. 12 - A 500 0-mL sample 01 pure water is allowed to come...Ch. 12 - Prob. 4SAQCh. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Which of these aqueous solutions hes the highest...Ch. 12 - Prob. 11SAQCh. 12 - Prob. 12SAQCh. 12 - Prob. 13SAQCh. 12 - Prob. 14SAQCh. 12 - Prob. 15SAQCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Use the data in the table to calculate the heats...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - A KCI solution containng 42 g of KCI per 100.0 g...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - An isotonic solution one with the same osmotic...Ch. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Distillation is a method of purification based on...Ch. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - Prob. 100ECh. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107E
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