Problem 12.1KSP Problem 12.2KSP Problem 12.3KSP Problem 12.4KSP Problem 12.1QP: Explain why liquids, unlike gases, are virtually incompressible. Problem 12.2QP: What is surface tension? What is the relationship between intermolecular forces and surface tension?... Problem 12.3QP Problem 12.4QP Problem 12.5QP Problem 12.6QP Problem 12.7QP Problem 12.8QP: Why does the viscosity of a liquid decrease with increasing temperature? Problem 12.9QP: Why is ice less dense than water? Problem 12.10QP Problem 12.11QP Problem 12.12QP Problem 12.13QP Problem 12.14QP: Predict which of the following liquids has greater surface tension: ethanol or (C2H5OH) dimethyl... Problem 12.15QP Problem 12.16QP: Vapor pressure measurements at several different temperatures are shown for mercury. Determine... Problem 12.17QP: The vapor pressure of liquid X is lower than that of liquid Y at 20C, but higher at 60C. What can... Problem 12.18QP Problem 12.19QP Problem 12.20QP: Define the following terms: crystalline solid, lattice point, unit cell, coordination number,... Problem 12.21QP Problem 12.22QP: Classify the solid states in terms of crystal types of the elements in the third period of the... Problem 12.23QP Problem 12.24QP: Define X-ray diffraction. What are the typical wavelengths (in nanometers) of X rays? (See Figure... Problem 12.25QP Problem 12.26QP: What is the coordination number of each sphere in (a) a simple cubic cell, (b) a body-centered cubic... Problem 12.27QP: Calculate the number of spheres that would be found within a simple cubic cell, body-centered cubic... Problem 12.28QP Problem 12.29QP: Barium metal crystallizes in a body-centered cubic lattice (the Ba atoms are at the lattice points... Problem 12.30QP Problem 12.31QP: Europium crystallizes in a body-centered cubic lattice (the Eu atoms occupy only the lattice... Problem 12.32QP: Crystalline silicon has a cubic structure. The unit cell edge length is 543 pm. The density of the... Problem 12.33QP Problem 12.34QP Problem 12.35QP Problem 12.36QP Problem 12.37QP: Shown here is a zinc oxide unit cell. What is the formula of zinc oxide? Problem 12.38QP: Describe and give examples of the following types of crystals: (a) ionic crystals, (b) covalent... Problem 12.39QP Problem 12.40QP: A solid is hard, brittle, and electrically nonconducting. Its melt (the liquid form of the... Problem 12.41QP: A solid is soft and has a low melting point (below 100C). The solid, its melt, and an aqueous... Problem 12.42QP Problem 12.43QP: Which of the following are molecular solids and which are covalent solids: Se8, HBr, Si, CO2, C,... Problem 12.44QP Problem 12.45QP Problem 12.46QP: What is a phase change? Name all possible changes that can occur among the vapor, liquid, and solid... Problem 12.47QP: What is the equilibrium vapor pressure of a liquid? How is it measured, and how does it change with... Problem 12.48QP: Use any one of the phase changes to explain what is meant by dynamic equilibrium. Problem 12.49QP: Define the following terms: (a) molar heat of vaporization, (b) molar heat of fusion, (c) molar heat... Problem 12.50QP Problem 12.51QP: What can we learn about the intermolecular forces in a liquid from the molar heat of vaporization? Problem 12.52QP: The greater the molar heat of vaporization of a liquid, the greater its vapor pressure. True or... Problem 12.53QP Problem 12.54QP: A closed container of liquid pentane (bp = 36.1C) is at room temperature. Why does the vapor... Problem 12.55QP: What is critical temperature? What is the significance of critical temperature in condensation of... Problem 12.56QP Problem 12.57QP: How do the boiling points and melting points of water and carbon tetrachloride vary with pressure?... Problem 12.58QP Problem 12.59QP Problem 12.60QP Problem 12.61QP: Which of the following phase transitions gives off more heat: (a) 1 mole of steam to 1 mole of water... Problem 12.62QP Problem 12.63QP Problem 12.64QP: Calculate the amount of heat (in kilo joules) required to convert 25.97 g of water to steam at 100C. Problem 12.65QP Problem 12.66QP: The molar heats of fusion and sublimation of lead are 4.77 and 182.8 kJ/mol, respectively. Estimate... Problem 12.67QP Problem 12.68QP: How is the rate of evaporation of a liquid affected by (a) temperature, (b) the surface area of a... Problem 12.69QP: Explain why steam at 100C causes more serious bums than water at 100C. Problem 12.70QP: The following compounds, listed with then- boiling points, are liquid at 10C: butane, 0.5C; ethanol,... Problem 12.71QP Problem 12.72QP Problem 12.73QP: Explain how waters phase diagram differs from those of most substances. What property of water... Problem 12.74QP: The blades of ice skates are quite thin, so the pressure exerted on ice by a skater can be... Problem 12.75QP: A length of wire is placed on top of a block of ice. The ends of the wire extend over the edges of... Problem 12.76QP Problem 12.77QP: A phase diagram of water is shown. Label the regions. Predict what would happen as a result of the... Problem 12.78QP Problem 12.79QP Problem 12.80QP Problem 12.81QP Problem 12.82QP Problem 12.83QP: The average distance between base pairs measured parallel to the axis of a DNA molecule is 3.4 . The... Problem 12.84QP: A CO2 fire extinguisher is located on the outside of a building in Massachusetts. During the winter... Problem 12.85QP: What is the vapor pressure of mercury at its normal boiling point (357C)? Problem 12.86QP Problem 12.87QP: The liquid-vapor boundary line in the phase diagram of any substance always stops abruptly at a... Problem 12.88QP Problem 12.89QP Problem 12.90QP: A student is given four solid samples labeled W, X, Y, and Z. All have a metallic luster. She is... Problem 12.91QP Problem 12.92QP: The diagram shows a kettle of boiling water. Identify the phases in regions A and B. Problem 12.93QP: The south pole of Mars is covered with solid carbon dioxide, which partly sublimes during the... Problem 12.94QP: The properties of gases, liquids, and solids differ in a number of respects. How would you use the... Problem 12.95QP: The standard enthalpy of formation of gaseous molecular iodine is 62.4 kJ/mol. Use this information... Problem 12.96QP Problem 12.97QP: Under the same conditions of temperature and density, which of the following gases would you expect... Problem 12.98QP: The distance between Li+ and Cl is 257 pm in solid LiCl and 203 pm in an LiCl unit in the gas phase.... Problem 12.99QP: Heat of hydration, that is, the heat change that occurs when ions become hydrated in solution, is... Problem 12.100QP: The fluorides of the second period elements and then melting points are: LiF, 845C; BeF2, 800C; BF3,... Problem 12.101QP: Calculate the H for the following processes at 25C: (a) Br2(l) Br2(g), (b) Br2(g) 2Br(g). Comment... Problem 12.102QP Problem 12.103QP Problem 12.104QP: Ozone (O3) is a strong oxidizing agent that can oxidize all the common metals except gold and... Problem 12.105QP: A sample of limestone (CaCO3) is heated in a closed vessel until it is partially decomposed. Write... Problem 12.106QP: Carbon and silicon belong to Group 4A of the periodic table and have the same valence election... Problem 12.107QP Problem 12.108QP: A 1.20-g sample of water is injected into an evacuated 5.00-L flask at 65C. What percentage of the... Problem 12.109QP: What are the advantages of cooking the vegetable broccoli with steam instead of boiling it water? Problem 12.110QP: A quantitative measure of how efficiently spheres pack into unit cells is called packing efficiency,... Problem 12.111QP: The phase diagram of helium is shown. Helium is the only known substance that has two different... Problem 12.112QP: The phase diagram of sulfur is shown. (a) How many triple points are there? (b) Which is the more... Problem 12.113QP Problem 12.114QP: Argon crystallizes in the face-centered cubic arrangement at 40 K. Given that the atomic radius of... Problem 12.115QP: Given the phase diagram of carbon, answer the following questions: (a) How many triple points are... Problem 12.116QP Problem 12.117QP: Swimming coaches sometimes suggest that a drop of alcohol (ethanol) placed in an ear plugged with... Problem 12.118QP Problem 12.119QP: Why do citrus growers spray their trees with water to protect them from freezing? Problem 12.120QP: Calcium metal crystallizes in a face-centered cubic unit cell with a cell edge length of 558.84 pm.... Problem 12.121QP: A student heated a beaker of cold water (on a tripod) with a Bunsen burner. When the gas was... Problem 12.122QP: The compound diclilorodifluoromethane (CCl2F2) has a normal boiling point of 30C, a critical... Problem 12.123QP: Iron crystallizes in a body-centered cubic lattice. The cell length as determined by X-ray... Problem 12.124QP: Sketch the cooling curves of water from about 110C to about 10C. How would you also show the... Problem 12.125QP Problem 12.126QP: A sampleof water shows the following behavior as it is heated at a constant rate. If twice the mass... Problem 12.127QP: A closed vessel of volume 9.6 L contains 2.0 g of water. Calculate the temperature (in C) at which... Problem 12.128QP: The electrical conductance of copper metal decreases with increasing temperature, but that of a... Problem 12.129QP: Assuming ideal behavior, calculate the density of gaseous HF at its normal boiling point (19.5C).... Problem 12.130QP: Explain why drivers are advised to use motor oil with lower viscosity in the winter and higher... Problem 12.131QP Problem 12.132QP: Silicon used in computer chips must have an impurity level below 109 (i.e., fewer than one impurity... Problem 12.133QP format_list_bulleted