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Interpretation: The hydrocarbons that are liquids at room temperature given in the table are to be determined. The trends in the melting and boiling points of the given hydrocarbons are to be described and the regular trend is to be identified. The types of intermolecular forces present in the given hydrocarbons are to be identified and the boiling point trend is to be explained on the basis intermolecular forces. The graph between boiling point and molar mass of hydrocarbons is to be drawn. From the graph drawn, the boiling point of heptane is to be predicted.
Concept Introduction: The lower mass hydrocarbons have low boiling point and usually, they evaporate at room temperature.
The hydrocarbon with higher molar mass exists as a liquid at room temperature.
The boiling point of hydrocarbon increases with increase of molar mass.
The dispersion force exists between the hydrocarbons.
Greater the dispersion forces, higher will be the boiling point.
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Chapter 12 Solutions
Introducing Chemistry
- Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)arrow_forwardNonearrow_forwardDraw the Lewis structure of C2H4Oarrow_forward
- a) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 productarrow_forwardNonearrow_forwardDr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v Varrow_forward
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