ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Anacin is an over-the-counter pain reliever that contains aspirin and caffeine. Answer the following questions about each compound.
a.What is the molecular formula?
b. How many lone pairs are present on heteroatoms?
c. Label the hybridization state of each carbon.
d. Draw three additional resonance structures.
5. Answer the following questions about the molecules CH2S (C is the centralatom).a. Draw the Lewis structure.b. Write the valence shell electron configuration for C.c. Draw the valence orbital diagram for C.d. Draw the hybridized orbital diagram for C.e. Give a bond description for each bond in the molecule.
Answer the following questions about octocrylene, a common sunscreen component.
a. What is the hybridization of each C atom?
b. How many lone pairs does octocrylene contain?
c. What is the geometry around each C atom?
d. Draw two additional resonance structures.
e. Label all polar bonds.
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- Draw an orbital picture of propene. The bond between and is formed by the overlap of which types of orbitals? a. sp2 and sp2 b. sp3 and sp3 c. sp2 on Ca and sp3 on Cb d. sp3 on Ca and sp2 on Cb The double bond between and is formed by what? a. two sigma bonds b. two pi bonds c. overlap of a p orbital on Cb with a sp2 orbital on Cc. d. overlap of two p orbitals plus overlap of two sp2 orbitalsarrow_forwardWhich can be used as a basis for identifying the type of orbital hybridization of a carbon atom given the Kekule or Lewis structure of the compound? Identify all that apply. Defend your answers. a. number of C atoms around carbon b. number of H atoms around carbon c. number of groups attached to the C atom d. number of lone electron pairs or unpaired electrons around the C atom e. type of bond (single, double, or triple) between C and other atoms around itarrow_forward. Draw the Lewis diagram for acetamide. ( CH3CONH2) a. What is the electron geometry around each of the two carbon atoms. b. What is the hybridization type of each of the carbon atoms. c. What are the bond types and orbitals involved in bonding for all bonds between the C and O atoms.arrow_forward
- Answer each question about L-dopa, a drug used since 1967 to treat Parkinson's disease. a.Convert the skeletal structure to a Lewis structure. b What is the hybridization and geometry around each labeled atom? c. Label three polar bonds.arrow_forwardIndicate the number of sp3-hybridized carbon atoms. Select one: a. 4 b. 6 c. 2 d. 8arrow_forwardCH3+ and CH3- are two highly reactive carbon species. a. What is the predicted hybridization and geometry around each carbon atom? b. Two electrostatic potential plots are drawn for these species. Which ion corresponds to which diagram and why?arrow_forward
- Benzene is especially stable due to a. the electrons of the double bonds are delocalized b. its planar shape c. the total number of carbons in the molecule d. each carbon has four bondsarrow_forwardAnswer the following questions about amoxicillin, an antibiotic from the penicillin family. NH2 H N. N. НО Но amoxicillin a. Predict the hybridization and geometry around each highlighted atom. b. Label five polar bonds using the symbols &+ and 8–. C. How many n bonds does amoxicillin have? Label them. d. Find a C- H bond containing a carbon atom having a hybrid orbital with 33% s-character.arrow_forward1 and 2 answer onlyarrow_forward
- Part B: Models 1. For each chemical formula given, draw the Lewis structure of each isomer that approximates the actual shape and name following IUPAC rules. When requested, give the hybridization of every central atom. a) C4H10 (2 isomers) abioe onimA (d mol of ertio doss iw toss anistur b) C3H6CI2 (4 isomers)arrow_forward18. What type of bonds hold organic molecules together? How are they different than the bonds that hold inorganic molecules together? Be specific, I want more than just names of bonds. 19. For the following molecule draw in all the dipole moments using 6+ and 6. XX 20. BONUS: Why can an sp² hybridized carbon not form a double bond? 7arrow_forwardAnswer the following questions about acetonitrile (CH;C=N:). c. In what type of orbital does the lone pair on N reside? d. Label all bonds as polar or nonpolar. a. Determine the hybridization of both C atoms and the N atom. b. Label all bonds as o or r.arrow_forward
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