Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 11.2C, Problem 11.2P

(a)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(b)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(c)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(d)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(e)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(f)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(g)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

(h)

Interpretation Introduction

To determine: The products of the reactions with the given compound.

Interpretation: The products of the reactions with the given compounds are to be stated.

Concept introduction: The combination of chromic acid or excess sodium hypochlorite with acetic acid is used for the conversion of secondary alcohols into ketone and primary alcohols or aldehyde into carboxylic acid through oxidation reaction.

The combination of PCCorNaOCl(1equivalent) with TEMPO is used for the conversion of primary alcohols into aldehyde and secondary alcohol into ketone through selective oxidation reaction.

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Chapter 11 Solutions

Organic Chemistry (9th Edition)

Ch. 11.6 - Predict the products of the following reactions....Ch. 11.7A - Propose a mechanism for the reaction of a....Ch. 11.7B - Prob. 11.13PCh. 11.7B - Show how you would use a simple chemical test to...Ch. 11.7C - Neopentyl alcohol, (CH3)3CCH2OH, reacts with...Ch. 11.7C - Prob. 11.16PCh. 11.7C - When cis-2-methylcyclohexanol reacts with the...Ch. 11.8 - Prob. 11.18PCh. 11.9 - Prob. 11.19PCh. 11.9 - Prob. 11.20PCh. 11.9 - Prob. 11.21PCh. 11.10A - Prob. 11.22PCh. 11.10A - Some alcohols undergo rearrangement or other...Ch. 11.10B - Prob. 11.24PCh. 11.10B - Explain why the acid-catalyzed condensation is a...Ch. 11.10B - Prob. 11.26PCh. 11.10B - When the following substituted cycloheptanol...Ch. 11.11A - Prob. 11.28PCh. 11.11A - Prob. 11.29PCh. 11.11B - Predict the products formed by periodic acid...Ch. 11.12 - Prob. 11.31PCh. 11.13A - Prob. 11.32PCh. 11.14 - Prob. 11.33PCh. 11.14 - a. Show how ethanol and cyclohexanol may be used...Ch. 11.14 - Prob. 11.35PCh. 11.14 - Phenols (pKa 10) are more acidic than other...Ch. 11.14 - To practice working through the early parts of a...Ch. 11.14 - Prob. 11.38PCh. 11 - Predict the major products of the following...Ch. 11 - Show how you would convert 2-methylcyclopentanol...Ch. 11 - In each case, show how you would synthesize the...Ch. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Both cis- and trans-2-methylcyclohexanol undergo...Ch. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Show how you would make each compound, beginning...Ch. 11 - Predict the major products (including...Ch. 11 - Show how you would use simple chemical tests to...Ch. 11 - The compound shown below has three different types...Ch. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Show how you would synthesize the following...Ch. 11 - Show how you would synthesize the following...Ch. 11 - The following pseudo-syntheses (guaranteed not to...Ch. 11 - Two unknowns, X and Y, both having the molecular...Ch. 11 - The Williamson ether synthesis involves the...Ch. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Alcohols combine with ketones and aldehydes to...Ch. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SP
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