ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Draw and describe the hybridization process of PROPENE, CH3CH=CH2. State the type of hybrid of each carbon, label all the bonds involve.
Methyl isocyanate, CH3 -N= C = O, is used in the industrial synthesis of a type of pesticide and herbicide known as a carbamate. As a historical note, an industrial accident in Bhopal, India, in 1984 resulted in leakage of an unknown quantity of this chemical into the air. An estimated 200,000 people were exposed to its vapors, and over 2000 of these people died.
Q.) Write a Lewis structure for methyl isocyanate and predict its bond angles. What is the hybridization of its carbonyl carbon? Of its nitrogen atom?
11. Which statement is true of the carbon-carbon bonds in benzene?
(a) They are identical to the carbon-carbon bonds in cyclohexane.
(b) They are identical to the carbon-carbon bonds in cyclohexene.
(c) They are half-way between a double and single bond.
(d) They are easily broken in chemical reactions.
(e) They are all double bonds.
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- The bonding between the carbon and oxygen in a ketone can be described as C(sp2)-0(sp²), o-bond and C(p)-O(p), л-bond. How would you describe the bonding between carbon and oxygen in a ketene? Sketch the orbitals used to make the bonds in the ketene. H a ketenearrow_forwardSodium triacetoxyborohydride, NaBH(OAc)3, is a mild reducing agent that reduces aldehydesmuch more quickly than ketones. It can be used to reduce aldehydes in the presence of ketones,such as in the following reaction:CH3 C CH2O OC H CH3 C CH2OCH2OHNaBH(OAc)3CH3COOH(a) Draw a complete Lewis structure for sodium triacetoxyborohydride.(b) Propose a mechanism for the reduction of an aldehyde by sodium triacetoxyborohydridearrow_forwardWhat is the hybridization of the C in this aldehyde?arrow_forward
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- For each of the following compounds, 1. draw the Lewis structure. 2. show how the bond dipole moments (and those of any nonbonding pairs of electrons) contribute to the molecular dipole moment. 3. estimate whether the compound will have a large, small, or zero dipole moment.arrow_forwardCaffeine is an aromatic compound. Using resonance structures, show how the sixmember ring can be drawn in its "benzoid" form. Indicate the hybridization of each nitrogen atom and specify the hybridization of the orbital occupied by each of the lone pairs.Write all possible reasonable resonance structures for the following compounds. Label the major and minor contributors to each resonance hybrid. N : Z— N:arrow_forwardGive the number of all of sigma bonds and all of the pi bonds for benzene, C6H6. H HIC I H 6 sigma bonds, 3 pi bonds 12 sigma bonds, 3 pi bonds 6 sigma bonds, 6 pi bonds O 3 sigma bonds, 6 pi bonds O 15 sigma bonds, 3 pi bondsarrow_forward
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