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Concept explainers
Interpretation:
The geometry of silicon atom in trimethylhydroxysilane has to be predicted
Concept Introduction:
According to VSEPR (Valence Shell Electron Pair Repulsion) theory, each molecule gets a unique structure. That structure is explained by considering steric number of that molecule.
The steric number is the combination of both number of
The geometry of the central atom will be determined by counting the steric number followed by the hybridization state of that central atom and finally electronic arrangement of atoms in space.
If the steric number is 4, the central atom has sp3 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be tetrahedral.
If the steric number is 3, the central atom has sp2 hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be trigonal planar.
If the steric number is 2, the central atom has sp hybridized and the electronic arrangement of atoms in space (i.e. geometry) will be linear.
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Chapter 1 Solutions
ORGANIC CHEMISTRY: W/ACCESS
- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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