CHEM: STRUC & PROP (LL) VOL 2 >C PKG<
2nd Edition
ISBN: 9780137390922
Author: Tro
Publisher: PEARSON C
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Chapter 11, Problem 92E
Interpretation Introduction
To determine:
Amount of liquid butane present.
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 11 Solutions
CHEM: STRUC & PROP (LL) VOL 2 >C PKG<
Ch. 11 - Why do ethanol and dimethyl ether have such...Ch. 11 - Why are intermolecular forces important?Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Which factors cause transitions between the solid...Ch. 11 - Describe the relationship between the state of a...Ch. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10E
Ch. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - What is the ion-dipole force? Why is it important?Ch. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - What is capillary action? How does it depend on...Ch. 11 - Explain what happens during the processes of...Ch. 11 - Why is vaporization endothermic? Why is...Ch. 11 - Prob. 20ECh. 11 - What is the heat of vaporization for a liquid, and...Ch. 11 - Explain the process of dynamic equilibrium. How is...Ch. 11 - What happens to a system in dynamic equilibrium...Ch. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Examine the heating curve for water in section...Ch. 11 - What is a phase diagram? What is the significance...Ch. 11 - Draw a generic phase diagram and label its...Ch. 11 - Prob. 35ECh. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Prob. 38ECh. 11 - Arrange these compounds in order of increasing...Ch. 11 - Prob. 40ECh. 11 - Pick the compound with the highest boiling point...Ch. 11 - Pick the compound with the highest boiling point...Ch. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Water (a) “wets” some surfaces and beads up on...Ch. 11 - The structures of two isomers of heptanes are...Ch. 11 - Prob. 50ECh. 11 - Water in a glass tube that contains grease or oil...Ch. 11 - When a thin glass tube is put into water, the...Ch. 11 - Which evaporates more quickly: 55 mL of water in a...Ch. 11 - Prob. 54ECh. 11 - Spilling room temperature water over your skin on...Ch. 11 - Prob. 56ECh. 11 - The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 58ECh. 11 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - How much energy is released when 65.8 g of water...Ch. 11 - Prob. 66ECh. 11 - An 8.5 g ice cube is placed into 255 g of water....Ch. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - The high-pressure phase diagram of ice is shown...Ch. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - How is the density of solid water compared to that...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Four ice cubes at exactly 00C with a total mass of...Ch. 11 - Prob. 86ECh. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Prob. 89ECh. 11 - A sealed flask contains 0.55 g of water at 280C....Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Given that the heat of fusion of water is —6.02...Ch. 11 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - A substance has a triple point at a temperature of...Ch. 11 - The boiling of three compounds are tabulated here....Ch. 11 - Prob. 108ECh. 11 - Based on the heating curve for water, does it take...Ch. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 1SAQCh. 11 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 11 - Taking intermolecular forces into account, which...Ch. 11 - What substance experiences dipole-dipole forces?...Ch. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Determine the amount of heat (in kJ) required to...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQCh. 11 - Prob. 11SAQCh. 11 - Determine which state this substance is in at 1...Ch. 11 - Prob. 13SAQ
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Similar questions
- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
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