The role of Pauli’s exclusion principle in stability of molecules.

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Draw a right-handed 3D Cartesian coordinate system (= x, y and z axes). Show a vector A with tail in the origin and sticking out in the positive x, y and z directions. Show the angles between A and the positive x, y and z axes, and call these angles α₁, α₂ and α3 Prove that Ax Acos α₁ Ay = Acos α₂ A₂- Acos α3

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Chapter 11, Problem 5Q

To determine

The role of Pauli’s exclusion principle in stability of molecules.

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Draw a right-handed 3D Cartesian coordinate system (= x, y and z axes). Show a vector A with tail in the origin and sticking out in the positive x, y and z directions. Show the angles between A and the positive x, y and z axes, and call these angles α₁, α₂ and α3 Prove that Ax Acos α₁ Ay = Acos α₂ A₂- Acos α3

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Draw a third quadrant vector C. (remember that boldface characters represent vector quantities). Show the standard angle 0 for this vector (= angle that C makes with the positive x- axis). Also show the angle that C makes with the negative y-axis: call the latter angle 8. Finally, show the smallest angles that C makes with the positive x-axis and the positive y-axis: call these angles p1 and p2, repectively. a) Prove the following formulas for the components of C involving the standard angle (hint: start with the formulas for the components based on the angle & and then use (look up if necessary) co-function identities linking cosine and sine of 8 to sine and cosine of 0 since 8 = 3π/2-8 (this will switch cosine and sine around and eliminate - signs as well)) - C=Ccose C₁=Csine b) Prove the following formulas for the components of C: C=Ccosp1 C=Ccosp2