PRINCIPLES OF MODERN CHEMISTRY-OWLV2
8th Edition
ISBN: 9781305271609
Author: OXTOBY
Publisher: CENGAGE L
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- A 1.40-g sample of polyethylene, a common plastic, is dissolved in enough organic solvent to give 100.0 mL of solution. What is the average molar mass of the polymer if the measured osmotic pressure of the solution is 1.86 mm Hg at 25 C?arrow_forwardA forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?arrow_forwardThe osmotic pressure of a solution containing 7.0 g of insulin per liter is 23 torr at 25 C. What is the molar mass of insulin?arrow_forward
- The vapor pressures of several solutions of water-propanol (CH3CH2CH2OH) were determined at various compositions, with the following data collected at 45C: H2O Vapor pressure(torr) 0 74.0 0.15 77.3 0.37 80.2 0.54 81.6 0.69 80.6 0.83 78.2 1.00 71.9 a. Are solutions of water and propanol ideal? Explain. b. Predict the sign of Hsoln for water-propanol solutions. c. Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. d. Which of the solutions in the data would have the lowest normal boiling point?arrow_forwardBradykinin is a small peptide (9 amino acids; 1060 g/mol) that lowers blood pressure by causing blood vessels to dilate. What is the osmotic pressure of a solution of this protein at 20 C if 0.033 g of the peptide is dissolved in water to give 50.0 mL of solution?arrow_forwardReserpine is a natural product isolated from the roots of the shrub Rauwolfia serpenlina. It was first synthesized in 1956 by Nobel Prize winner R. B. Woodward. It is used as a tranquilizer and sedative. When 1.00 g reserpine is dissolved in 25.0 g camphor, the freezing-point depression is 2.63C (Kr for camphor is 40.C kg/mol). Calculate the molality of the solution and the molar mass of reserpine.arrow_forward
- Solutions Introduced directly into the bloodstream have to be isotonic with blood; that is, they must have the same osmotic pressure as blood. An aqueous NaCl solution has to be 0.90% by mass to be isotonic with blood. What is the molarity of the sodium ions in solution? Take the density of the solution to be 1.00 g/mL.arrow_forwardAn aqueous solution of sodium bromide freezes at 1.61 C. What is the total molality of solute particles? How many grams of sodium bromide are present in 1 kg of water? (Assume an ideal value for the vant Hoff factor.)arrow_forwardRationalize the temperature dependence of the solubility of a gas in water in terms of the kinetic molecular theory.arrow_forward
- Consider two solutions at a certain temperature. Solution X has a nonelectrolyte as a solute and an osmotic pressure of 1.8 atm. Solution Y also has a nonelectrolyte as a solute and an osmotic pressure of 4.2 atm. What is the osmotic pressure of a solution made up of equal volumes of solutions X and Y at the same temperature? Assume that the volumes are additive.arrow_forwardYou make 20.0 g of a sucrose (C12H22O11) and NaCl mixture and dissolve it in 1.00 kg water. The freezing point of this solution is found to be 0.426C. Assuming ideal behavior, calculate the mass percent composition of the original mixture, and the mole fraction of sucrose in the original mixture.arrow_forwardA compound contains 42.9% C, 2.4% H, 16.6% N, and 38.1% O. The addition of 3.16 g of this compound to 75.0 mL of cyclohexane (d=0.779g/mL) gives a solution with a freezing point at 0.0C. Using Table 10.2, determine the molecular formula of the compound.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY