Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134554563
Author: Brown
Publisher: PEARSON
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Chapter 11, Problem 50E
Interpretation Introduction
To determine: If the vapor pressure of acetone is higher or lower than ethanol at
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 11 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 11.2 - Which of the following substances is most likely...Ch. 11.2 - Prob. 11.1.2PECh. 11.3 - Prob. 11.2.1PECh. 11.3 - Prob. 11.2.2PECh. 11.4 - What information about water is needed to...Ch. 11.4 - Prob. 11.3.2PECh. 11.5 -
In the mountains, water in an open container will...Ch. 11.5 - Prob. 11.4.2PECh. 11.6 - Prob. 11.5.1PECh. 11.6 - Prob. 11.5.2PE
Ch. 11.7 - Liquid crystalline phases are produced by which of...Ch. 11.7 - Prob. 11.6.2PECh. 11 - Prob. 1DECh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3ECh. 11 - If 42.0 kj of heat is added to a 32.0-g sample of...Ch. 11 - Prob. 5ECh. 11 - The molecules have the same molecular formula...Ch. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Describe the intermolecular forces that must be...Ch. 11 - Prob. 18ECh. 11 - List the following molecules in order of...Ch. 11 - True or false: a. For molecules with similar...Ch. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - A number of salts containing the tetrahedral...Ch. 11 - Prob. 32ECh. 11 - a. What is the relationship between surface...Ch. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - The boiling points, surface tension, and...Ch. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - 11.43 For many years drinking water has been...Ch. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - The fluorocarbon compound C2 Cl 3£'y has a normal...Ch. 11 - 11.47 Indicate whether each statement is true or...Ch. 11 - Prob. 48ECh. 11 - 11,49 Which of the following affects the vapor...Ch. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - In terms of the arrangement and freedom of motion...Ch. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73AECh. 11 - Prob. 74AECh. 11 - Prob. 75AECh. 11 - Prob. 76AECh. 11 - Prob. 77AECh. 11 - The table below shows the normal boiling points of...Ch. 11 - Prob. 79AECh. 11 - Prob. 80AECh. 11 - Prob. 81AECh. 11 - Prob. 82AECh. 11 - Prob. 83AECh. 11 - Prob. 84AECh. 11 - Prob. 85AECh. 11 - Prob. 86AECh. 11 - Prob. 87AECh. 11 - Prob. 88AECh. 11 - Prob. 89AECh. 11 - Prob. 90IECh. 11 - Prob. 91IECh. 11 - Prob. 92IECh. 11 - 11.93 The vapor pressure of ethanol (C2H5OH) at 19...Ch. 11 - Prob. 94IECh. 11 - Prob. 95IECh. 11 - Prob. 96IECh. 11 - Prob. 97IE
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- Germanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap? Group of answer choices It is impossible to dope Ge and have this result in a larger bandgap. Dope the Ge with silicon (Si) Dope the Ge with gallium (Ga) Dope the Ge with phosphorus (P)arrow_forwardWhich of the following semiconductors would you choose to have photons with the longest possible wavelengths be able to promote electrons to the semiconductor's conduction band? Group of answer choices Si Ge InSb CdSarrow_forwardWhich of the following metals is the only one with all of its bands completely full? Group of answer choices K Na Ca Alarrow_forward
- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forwardFrom an energy standpoint, which two process - in the correct order - are involved in the dissolving of an ionic compound crystal? Group of answer choices Water coordination to the ions followed by sublimation into the gas phase Sublimation of the crystal into gas-phase ions followed by water coordination to the ions Ion dissociation from the crystal followed by water coordination to the ions Water coordination to the ions followed by ion dissociation from the crystalarrow_forward
- For which Group 2 metal (M), is this process the most exothermic? M2+(g) + O2−(g) + CO2(g) → MO(s) + CO2(g) Group of answer choices M = Sr M = Mg M = Ca M = Baarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); R₂BH (6); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI Solvent Reagent(s) Solvent Reagent(s) HO OHarrow_forwardFor which of the following ionic compounds would you expect the smallest difference between its theoretical and experimental lattice enthalpies? (You may assume these all have the same unit cell structure.) Electronegativities: Ca (1.0), Fe (1.8), Mg (1.2), O (3.5), S (2.5), Zn (1.6) Group of answer choices ZnO MgS CaO FeSarrow_forward
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