Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134566290
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 11, Problem 47E
Interpretation Introduction
To determine:
To find the compound that has greater surface tension acetone or water.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 11 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: Structure and Properties (2nd Edition)
Ch. 11 - Why do ethanol and dimethyl ether have such...Ch. 11 - Why are intermolecular forces important?Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Which factors cause transitions between the solid...Ch. 11 - Describe the relationship between the state of a...Ch. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10E
Ch. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - What is the ion-dipole force? Why is it important?Ch. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - What is capillary action? How does it depend on...Ch. 11 - Explain what happens during the processes of...Ch. 11 - Why is vaporization endothermic? Why is...Ch. 11 - Prob. 20ECh. 11 - What is the heat of vaporization for a liquid, and...Ch. 11 - Explain the process of dynamic equilibrium. How is...Ch. 11 - What happens to a system in dynamic equilibrium...Ch. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Examine the heating curve for water in section...Ch. 11 - What is a phase diagram? What is the significance...Ch. 11 - Draw a generic phase diagram and label its...Ch. 11 - Prob. 35ECh. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Prob. 38ECh. 11 - Arrange these compounds in order of increasing...Ch. 11 - Prob. 40ECh. 11 - Pick the compound with the highest boiling point...Ch. 11 - Pick the compound with the highest boiling point...Ch. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Water (a) “wets” some surfaces and beads up on...Ch. 11 - The structures of two isomers of heptanes are...Ch. 11 - Prob. 50ECh. 11 - Water in a glass tube that contains grease or oil...Ch. 11 - When a thin glass tube is put into water, the...Ch. 11 - Which evaporates more quickly: 55 mL of water in a...Ch. 11 - Prob. 54ECh. 11 - Spilling room temperature water over your skin on...Ch. 11 - Prob. 56ECh. 11 - The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 58ECh. 11 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - How much energy is released when 65.8 g of water...Ch. 11 - Prob. 66ECh. 11 - An 8.5 g ice cube is placed into 255 g of water....Ch. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - The high-pressure phase diagram of ice is shown...Ch. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - How is the density of solid water compared to that...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Four ice cubes at exactly 00C with a total mass of...Ch. 11 - Prob. 86ECh. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Prob. 89ECh. 11 - A sealed flask contains 0.55 g of water at 280C....Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Given that the heat of fusion of water is —6.02...Ch. 11 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - A substance has a triple point at a temperature of...Ch. 11 - The boiling of three compounds are tabulated here....Ch. 11 - Prob. 108ECh. 11 - Based on the heating curve for water, does it take...Ch. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 1SAQCh. 11 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 11 - Taking intermolecular forces into account, which...Ch. 11 - What substance experiences dipole-dipole forces?...Ch. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Determine the amount of heat (in kJ) required to...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQCh. 11 - Prob. 11SAQCh. 11 - Determine which state this substance is in at 1...Ch. 11 - Prob. 13SAQ
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