Chapter 11, Problem 33P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:  ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.