The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined. Conceptual introduction: The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding. The force of attraction between the same atoms of different molecules is called van der Waals force of attraction. The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction. The force of attraction between the two polar compounds is called as dipole-dipole interaction. To determine: The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Question

Want to see more full solutions like this?

Answer 1

Question

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Students have asked these similar questions

An expression for the root mean square velocity, vrms, of a gas was derived. Using Maxwell’s velocity distribution, one can also calculate the mean velocity and the most probable velocity (mp) of a collection of molecules. The equations used for these two quantities are vmean=(8RT/πM)1/2 and vmp=(2RT/M)1/2 These values have a fixed relationship to each other.(a) Arrange these three quantities in order of increasing magnitude.(b) Show that the relative magnitudes are independent of the molar mass of the gas.(c) Use the smallest velocity as a reference for establishing the order of magnitude and determine the relationship between the larger and smaller values.

The reaction of solid dimethylhydrazine, (CH3)2N2H2, and liquefied dinitrogen tetroxide, N2O4, has been investigated for use as rocket fuel. The reaction produces the gases carbon dioxide (CO2), nitrogen (N2), and water vapor (H2O), which are ejected in the exhaust gases. In a controlled experiment, solid dimethylhydrazine was reacted with excess dinitrogen tetroxide, and the gases were collected in a closed balloon until a pressure of 2.50 atm and a temperature of 400.0 K were reached.(a) What are the partial pressures of CO2, N2, and H2O?(b) When the CO2 is removed by chemical reaction, what are the partial pressures of the remaining gases?

One liter of chlorine gas at 1 atm and 298 K reacts completely with 1.00 L of nitrogen gas and 2.00 L of oxygen gas at the same temperature and pressure. A single gaseous product is formed, which fills a 2.00 L flask at 1.00 atm and 298 K. Use this information to determine the following characteristics of the product:(a) its empirical formula;(b) its molecular formula;(c) the most favorable Lewis formula based on formal charge arguments (the central atom is N);(d) the shape of the molecule.

Answer 2

Question

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Answer 6

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.

Conclusion

Methylamine has stronger intermolecular force of attraction between its two molecule compared to that of ammonia.

Answer 7

Chapter 11, Problem 1DE

Interpretation Introduction

Interpretation:

The molecule that has a stronger force of attraction between ammonia and methylamine and the reasons for the same is to be determined. Also, based on the reasons, list the other experiment that is done with these molecules to test the same hypothesis is to be determined.

Conceptual introduction:

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

The force of attraction between the same atoms of different molecules is called van der Waals force of attraction.

The force of attraction between the charged ion and a polar compound is called ionic-dipole interaction.

The force of attraction between the two polar compounds is called as dipole-dipole interaction.

To determine:

The molecule that has a stronger force of attraction from ammonia and methylamine and the reasons for the same.

Answer 8

Expert Solution & Answer

Answer to Problem 1DE

Solution: The molecule that has a stronger force of attraction from ammonia and methylamine is methylamine and the reasons for the same are stated below.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Explanation of Solution

The force of attraction between the hydrogen and an electronegative atom is called hydrogen bonding.

Nitrogen is an electronegative atom compared to hydrogen. Therefore, there exist the hydrogen bonding interaction between the nitrogen of one ammonia molecule and the hydrogen of another ammonia molecule.

Thus, the liquification of ammonia gas is easier.

According to the given data, methylamine is liquefied more easily than ammonia, since, the boiling point of ammonia is less than that of methylamine.

Therefore, the interaction between the two methylamine molecules is stronger than that between two ammonia molecules.

The reason for this is that the interaction between the two methylamine molecules other than hydrogen bonding exist, that is, van der Waals forces. This is due to the hydrophobic regions of the two different molecules and the dipole-dipole interaction present between the carbon and the nitrogen atom in a molecule.

The solubility of a salt of methyl ammine is stronger than that of ammonia, since in methylammonium ion, the positive charge is stabilized by the positive inductive effect of the methyl group. This effect is absent in an ammonium ion.

The pKa of protonated ammonia and protonated methylamine is 9.26 and 10.66 , respectively.

Therefore, ammonia is less basic than methylamine. This is due to the inductive effect of methyl group that pushes electrons to extract a proton much easily. This effect is absent in ammonia.