EBK PHYSICAL UNIVERSE
15th Edition
ISBN: 9780100255036
Author: KRAUSKOPF
Publisher: YUZU
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Chapter 11, Problem 16MC
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10. Imagine you have a system in which you have 54 grams of ice. You can melt this
ice and then vaporize it all at 0 C. The melting and vaporization are done reversibly
into a balloon held at a pressure of 0.250 bar. Here are some facts about water you
may wish to know. The density of liquid water at 0 C is 1 g/cm³. The density of ice at 0
C is 0.917 g/cm³. The enthalpy of vaporization of liquid water is 2.496 kJ/gram and the
enthalpy of fusion of solid water is 333.55 J/gram.
Consider 1 mole of supercooled water at -10°C. Calculate the entropy change of the water when the
supercooled water freezes at -10°C and 1 atm.
Useful data:
Cp (ice) = 38 J mol-1 K-1
Cp (water) 75J mol −1
K
-1
Afus H (0°C) 6026 J mol −1
Assume Cp (ice) and Cp (water) to be independent of temperature.
The molar enthalpy of vaporization of benzene at its normal boiling point (80.09°C) is 30.72 kJ/mol.
Assuming that AvapH and AvapS stay constant at their values at 80.09°C, calculate the value of
AvapG at 75.0°C, 80.09°C, and 85.0°C.
Hint: Remember that the liquid and vapor phases will be in equilibrium at the normal boiling point.
Chapter 11 Solutions
EBK PHYSICAL UNIVERSE
Ch. 11 - Prob. 1MCCh. 11 - Prob. 2MCCh. 11 - Prob. 3MCCh. 11 - Prob. 4MCCh. 11 - Prob. 5MCCh. 11 - Prob. 6MCCh. 11 - Prob. 7MCCh. 11 - Prob. 8MCCh. 11 - Prob. 9MCCh. 11 - Prob. 10MC
Ch. 11 - Prob. 11MCCh. 11 - Suppose there were molecules that had no...Ch. 11 - Prob. 13MCCh. 11 - Prob. 14MCCh. 11 - Prob. 15MCCh. 11 - Prob. 16MCCh. 11 - Prob. 17MCCh. 11 - Prob. 18MCCh. 11 - Prob. 19MCCh. 11 - Prob. 20MCCh. 11 - Prob. 21MCCh. 11 - Prob. 22MCCh. 11 - Prob. 23MCCh. 11 - Prob. 24MCCh. 11 - Prob. 25MCCh. 11 - Prob. 26MCCh. 11 - Prob. 27MCCh. 11 - Prob. 28MCCh. 11 - Prob. 29MCCh. 11 - Prob. 30MCCh. 11 - Prob. 31MCCh. 11 - Prob. 32MCCh. 11 - Prob. 33MCCh. 11 - Prob. 34MCCh. 11 - Prob. 35MCCh. 11 - Prob. 36MCCh. 11 - Prob. 37MCCh. 11 - Prob. 38MCCh. 11 - Prob. 39MCCh. 11 - Prob. 40MCCh. 11 - Prob. 41MCCh. 11 - Prob. 42MCCh. 11 - Prob. 1ECh. 11 - What kind of solid is ice? Why does ice float when...Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - How could you tell experimentally whether a...Ch. 11 - From which class of solids would you expect...Ch. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Van der Waals forces are strong enough to hold...Ch. 11 - Prob. 10ECh. 11 - What ions would you expect to find in the crystal...Ch. 11 - Why is the solubility of one gas in another...Ch. 11 - Why do bubbles of gas form in a glass of soda...Ch. 11 - Ordinary tap water tastes different after it has...Ch. 11 - How do unsaturated, saturated, and supersaturated...Ch. 11 - Prob. 16ECh. 11 - Give two ways to tell whether a sugar solution is...Ch. 11 - At 10C, which is more concentrated, a saturated...Ch. 11 - Prob. 19ECh. 11 - What is the difference between a molecular ion and...Ch. 11 - How could you distinguish experimentally between...Ch. 11 - Prob. 22ECh. 11 - You have a solution that contains Cl- ions and...Ch. 11 - You have a solution that contains Ca2+ ions and...Ch. 11 - You have a solution that contains Ag+ ions and...Ch. 11 - What is the easiest way to distinguish between a...Ch. 11 - Prob. 27ECh. 11 - Seawater freezes at a lower temperature than pure...Ch. 11 - Prob. 29ECh. 11 - What are the two chief ions found in seawater?Ch. 11 - (a) Is the percentage of the worlds water that is...Ch. 11 - The pesticide DDT concentrates in the fat of...Ch. 11 - Prob. 33ECh. 11 - Which of the following are weak acids?...Ch. 11 - Would you expect HBr to be a weak or strong acid?...Ch. 11 - Even though ammonia is not a base because its...Ch. 11 - What is the difference, if any, between a basic...Ch. 11 - Is it correct to say that the only ions an acidic...Ch. 11 - Which is more strongly acidic, a solution of pH 3...Ch. 11 - In an acidic solution, why is the OH concentration...Ch. 11 - Prob. 41ECh. 11 - When a salt that contains the negative ion of a...Ch. 11 - Prob. 43ECh. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of calcium...Ch. 11 - What salt is formed when a solution of sodium...Ch. 11 - What salt is formed when a solution of potassium...Ch. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Boric acid (H3BO3) is a very weak acid. What would...Ch. 11 - The Al3+ ion tends to form AlOH2+ ions in water...Ch. 11 - Prob. 52ECh. 11 - Prob. 53E
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- 3. The entropy of an ideal gas is S = Nkg In V. Entropy is a state function rather than a path function, and in this problem, you will show an example of the entropy change for an ideal gas being the same when you go between the same two states by two different pathways. A. Express ASV = S2 (V2) - S₁(V1), the change in entropy upon changing the volume from V₁to V2, at fixed particle number N and energy, U. B. Express ASN = S₂(N₂) - S₁ (N₁), the change in entropy upon changing the particle number from N₁ to N2, at fixed volume V and energy U. C. Write an expression for the entropy change, AS, for a two-step process (V₁, N₁) → (V2, N₁) → (V2, N₂) in which the volume changes first at fixed particle number, then the particle number changes at fixed volume. Again, assume energy is constant.arrow_forwardPlease don't use Chatgpt will upvote and give handwritten solutionarrow_forward6. We used the constant volume heat capacity, Cv, when we talked about thermodynamic cycles. It acts as a proportionality constant between energy and temperature: dU = C₁dT. You can also define a heat capacity for constant pressure processes, Cp. You can think of enthalpy playing a similar role to energy, but for constant pressure processes δαρ C = (37) - Sup Ср ат P = ат Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy and Cp for an ideal gas.arrow_forward
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