Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134112831
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 11, Problem 16E
Interpretation Introduction
To determine: The viscosity, its dependence on intermolecular forces, and the factors that affect viscosity.
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 11 Solutions
Chemistry: A Molecular Approach (4th Edition)
Ch. 11 - Prob. 1SAQCh. 11 - Q2. Liquid nitrogen boils at 77 K. The image shown...Ch. 11 - Q3. Based on the expected intermolecular forces,...Ch. 11 - Q4. Which substance experiences dipole–dipole...Ch. 11 - Q5. One of these substances is a liquid at room...Ch. 11 - Prob. 6SAQCh. 11 - Q7. Determine the amount of heat (in kJ) required...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQ
Ch. 11 - Prob. 1ECh. 11 - 2. Why are intermolecular forces important?
Ch. 11 - 3. What are the main properties of liquids (in...Ch. 11 - 4. What are the main properties of solids (in...Ch. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - 13. What is hydrogen bonding? How can you predict...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - 19. Why is vaporization endothermic? Why is...Ch. 11 - 20. How is the volatility of a substance related...Ch. 11 - 21. What is the heat of vaporization for a liquid...Ch. 11 - 22. Explain the process of dynamic equilibrium....Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - 26. What is the Clausius–Clapeyron equation and...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - 31. Examine the heating curve for water in Section...Ch. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - 39. Arrange these compounds in order of increasing...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - 50. Explain why the viscosity of multigrade motor...Ch. 11 - 51. Water in a glass tube that contains grease or...Ch. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - 57. The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - Prob. 65ECh. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - 72. How much heat (in kJ) is evolved in converting...Ch. 11 - Prob. 73ECh. 11 - 74. Consider the phase diagram for iodine shown...Ch. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - 82. How is the density of solid water compared to...Ch. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - 90. A sample of steam with a mass of 0.552 g and...Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - 94. A sealed flask contains 0.55 g of water at 28...Ch. 11 - Prob. 95ECh. 11 - 96. Consider a planet where the pressure of the...Ch. 11 - Prob. 97ECh. 11 - 98. Given that the heat of fusion of water is...Ch. 11 - 99. The heat of combustion of CH4 is 890.4 kJ/mol,...Ch. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - 102. Butane (C4H10) has a heat of vaporization of...Ch. 11 - Prob. 103ECh. 11 - 104. One prediction of global warming is the...Ch. 11 - Prob. 105ECh. 11 - Prob. 106ECh. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113QGWCh. 11 - Prob. 114QGWCh. 11 - Prob. 115QGWCh. 11 - Prob. 116QGWCh. 11 - 117. Students in a chemistry laboratory course are...
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- n Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forward
- Part VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forwardPart IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward
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