Chapter 11, Problem 14P

Arsenic acid, H3AsO4, is a poisonous acid that has been used in the treatment of wood to prevent insect damage. Arsenic acid has three acidic protons. Say you take a 25.00-mL sample of arsenic acid and prepare it for titration with NaOH by adding 25.00 mL of water. The complete neutralization of this solution requires the addition of 53.07 mL of 0.6441 M NaOH solution. Write the balanced chemical reaction for the titration, and calculate the molarity of the arsenic acid sample.

Consider the following generic equation OH(aq)+HB(aq) B(aq)+H2OFor which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) hydrochloric acid and pyridine, C5H5N (b) sulfuric acid and rubidium hydroxide (c) potassium hydroxide and hydrofluoric acid (d) ammonia and hydriodic acid (e) strontium hydroxide and hydrocyanic acid

A soluble iodide was dissolved in water. Then an excess of silver nitrate, AgNO3, was added to precipitate all of the iodide ion as silver iodide, AgI. If 1.545 g of the soluble iodide gave 2.185 g of silver iodide, how many grams of iodine are in the sample of soluble iodide? What is the mass percentage of iodine, I, in the compound?

Sodium chloride is used in intravenous solutions for medical applications. The NaCl concentration in such solutions must be accurately known and can be assessed by reacting the solution with an experimentally determined volume of AgNO3 solution of known concentration. The net ionic equation is Ag+(aq)+Cl(aq)AgCl(s) Suppose that a chemical technician uses 19.3 mL of 0.200-M AgNO3 to convert all the NaCl in a 25.0-mL sample of an intravenous solution to AgCl. Calculate the molarity of NaCl in the solution.

Twenty-five mL of a 0.388 M solution of Na2SO4 is mixed with 35.3 mL of 0.229 M Na2SO4. What is the molarity of the resulting solution? Assume that the volumes are additive.

What volume of 0.250 M HCI is required to neutralize each of the following solutions? a. 25.0 mL of 0.103 M sodium hydroxide, NaOH b. 50.0 mL of 0.00501 M calcium hydroxide, Ca(OH)2 c. 20.0 mL of 0.226 M ammonia, NH3 d. 15.0 mL of 0.0991 M potassium hydroxide, KOH

Consider the following generic equation: H+(aq)+ B(aq)HB(aq)For which of the following pairs would this be the correct prototype equation for the acid-base reaction in solution? If it is not correct, write the proper equation for the acid-base reaction between the pair. (a) nitric acid and calcium hydroxide (b) hydrochloric acid and CH3NH2 (c) hydrobromic acid and aqueous ammonia (d) perchloric acid and barium hydroxide (e) sodium hydroxide and nitrous acid

Potassium hydrogen phthalate, KHC8H4O4, is used to standardize solutions of bases. The acidic anion reacts with bases according to this net ionic equation: A 0.902-g sample of potassium hydrogen phthalate requires 26.45 mL NaOH to react; determine the molarity of the NaOH.

You are given a solid mixture of NaNO2 and NaCl and are asked to analyze it for the amount of NaNO2 present. To do so, you allow the mixture to react with sulfamic acid, HSO3NH2, in water according to the equation NaNO2(aq) + HSO3NH2(aq) NaHSO4(aq) + H2O() + N2(g) What is the weight percentage of NaNO2 in 1.232 g of the solid mixture if reaction with sulfa-mic acid produces 295 mL of dry N2 gas with a pressure of 713 mm Hg at 21.0 C?