(a) Interpretation: Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K d is 1 μm. Concept introduction: The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Question

12. When glutamic acid is heated to 180°C., it loses a molecule of water to form a lactam. The bond that creates the lactam is an amide bond that forms between the amino nitrogen and the carbon of the side chain -COOH group. What is the most reasonable structure for this lactam? (NOTE: The structure of glutamic acid is shown in Question 1.) COOH COOH ا کچھ جو کچھ C D COOH B COOH E COOH

Answer 1

Question

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

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12. When glutamic acid is heated to 180°C., it loses a molecule of water to form a lactam. The bond that creates the lactam is an amide bond that forms between the amino nitrogen and the carbon of the side chain -COOH group. What is the most reasonable structure for this lactam? (NOTE: The structure of glutamic acid is shown in Question 1.) COOH COOH ا کچھ جو کچھ C D COOH B COOH E COOH

10. Which one of the following compounds is the major organic product of the series of reactions shown here? Ph A OH Ph B CO₂Et Br -H Ν ΚΑ CO₂Et 1. NaOEt 1. NaOH, H₂O 2. H3O+ 2. PhCH2CH2Br 3. heat NH2 Ph OH NH2 0 OH Ph OH NH2 Ph D NH2 E OH

1. What is the isoelectric point of glutamic acid? (Glutamic acid has pKa1 2.10, pKa2 4.07, pKaз 9.47) A) pH 2.1 D) pH 6.8 B) pH 3.1 C) pH 4.1 E) pH 9.5 HO NH2 Glutamic acid (shown without charges) OH

Answer 2

Question

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Expert Solution & Answer

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Answer 3

Question

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Expert Solution & Answer

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Answer 4

Question

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 6

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 7

Chapter 11, Problem 13P

Interpretation Introduction

(a) Interpretation:

Calculation of the fraction of monomers that exist in the heterodimer complex of the total concentration of A+B inside the cell is 5 μm and K_d is 1 μm.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 8

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 9

Interpretation Introduction

(b) Interpretation:

Calculation of the fractions of monomers if the cell is now disrupted in the buffer, the cell contents are diluted 5-fold.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 10

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 11

Interpretation Introduction

(c) Interpretation:

The methods of detection of multiprotein complexes in cell-free homogenatesand discuss the methods of detection of the proteins.

Concept introduction:

The protein has a complex structure in which two monomers in their dimer form make the complex for effective function. The degree of saturation is termed as the fraction of monomer that has bonded with ligand in a protein complex.

Answer 12

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Ch. 11 - Prob. 1P Ch. 11 - Prob. 2P Ch. 11 - a. NAD+ kinase catalyzes the ATP-dependent...Ch. 11 - Prob. 4P Ch. 11 - Prob. 5P Ch. 11 - Prob. 6P Ch. 11 - Prob. 7P Ch. 11 - Consider the simple bimolecular reaction...Ch. 11 - Prob. 9P Ch. 11 - Prob. 10P

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