
Chemistry: Structure and Properties (2nd Edition)
2nd Edition
ISBN: 9780134293936
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 11, Problem 11E
Interpretation Introduction
To determine:
- What is the dipole-dipole force?
- How can we predict the presence of dipole-dipole forces in a compound?
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How many signals do you expect in the H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
For the molecule in the bottom drawing area, highlight in red any other H atoms that will
contribute to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in bottom
molecule
In the drawing area below, draw the major products of this organic reaction:
1. NaOH
?
2. CH3Br
If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area
instead.
No reaction.
Click and drag to start drawing a
structure.
☐ : A
ค
Predict the major products of the following organic reaction:
NC
Δ
?
Some important Notes:
• Draw the major product, or products, of the reaction in the drawing area below.
• If there aren't any products, because no reaction will take place, check the box below the drawing area instead.
• Be sure to draw bonds carefully to show important geometric relationships between substituents.
Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the
ring structure. You can add any substituents using the pencil tool in the usual way.
Click and drag to start drawing a
structure.
Х
а
Chapter 11 Solutions
Chemistry: Structure and Properties (2nd Edition)
Ch. 11 - Why do ethanol and dimethyl ether have such...Ch. 11 - Why are intermolecular forces important?Ch. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Which factors cause transitions between the solid...Ch. 11 - Describe the relationship between the state of a...Ch. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10E
Ch. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - What is the ion-dipole force? Why is it important?Ch. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - What is capillary action? How does it depend on...Ch. 11 - Explain what happens during the processes of...Ch. 11 - Why is vaporization endothermic? Why is...Ch. 11 - Prob. 20ECh. 11 - What is the heat of vaporization for a liquid, and...Ch. 11 - Explain the process of dynamic equilibrium. How is...Ch. 11 - What happens to a system in dynamic equilibrium...Ch. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Examine the heating curve for water in section...Ch. 11 - What is a phase diagram? What is the significance...Ch. 11 - Draw a generic phase diagram and label its...Ch. 11 - Prob. 35ECh. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Determine the kinds of intermolecular forces that...Ch. 11 - Prob. 38ECh. 11 - Arrange these compounds in order of increasing...Ch. 11 - Prob. 40ECh. 11 - Pick the compound with the highest boiling point...Ch. 11 - Pick the compound with the highest boiling point...Ch. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Water (a) “wets” some surfaces and beads up on...Ch. 11 - The structures of two isomers of heptanes are...Ch. 11 - Prob. 50ECh. 11 - Water in a glass tube that contains grease or oil...Ch. 11 - When a thin glass tube is put into water, the...Ch. 11 - Which evaporates more quickly: 55 mL of water in a...Ch. 11 - Prob. 54ECh. 11 - Spilling room temperature water over your skin on...Ch. 11 - Prob. 56ECh. 11 - The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 58ECh. 11 - Suppose that 0.95 g of water condenses on a 75.0 g...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - How much energy is released when 65.8 g of water...Ch. 11 - Prob. 66ECh. 11 - An 8.5 g ice cube is placed into 255 g of water....Ch. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Prob. 74ECh. 11 - Prob. 75ECh. 11 - The high-pressure phase diagram of ice is shown...Ch. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - How is the density of solid water compared to that...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Four ice cubes at exactly 00C with a total mass of...Ch. 11 - Prob. 86ECh. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Prob. 89ECh. 11 - A sealed flask contains 0.55 g of water at 280C....Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Given that the heat of fusion of water is —6.02...Ch. 11 - The heat of combustion of CH4 is 890.4 kJ/mol, and...Ch. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Prob. 104ECh. 11 - Prob. 105ECh. 11 - A substance has a triple point at a temperature of...Ch. 11 - The boiling of three compounds are tabulated here....Ch. 11 - Prob. 108ECh. 11 - Based on the heating curve for water, does it take...Ch. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 1SAQCh. 11 - Liquid nitrogen boils at 77 K. This image depicts...Ch. 11 - Taking intermolecular forces into account, which...Ch. 11 - What substance experiences dipole-dipole forces?...Ch. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Determine the amount of heat (in kJ) required to...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQCh. 11 - Prob. 11SAQCh. 11 - Determine which state this substance is in at 1...Ch. 11 - Prob. 13SAQ
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- Predict the major products of this organic reaction. Be sure you use dash and wedge bonds to show stereochemistry where it's important. + ☑ OH 1. TsCl, py .... 文 P 2. t-BuO K Click and drag to start drawing a structure.arrow_forwardConsider this organic reaction: ( Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. Click and drag to start drawing a structure. Х : а ค 1arrow_forwardIn the drawing area below, draw the major products of this organic reaction: If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. 1. NaH 2. CH3Br ? Click and drag to start drawing a structure. No reaction. : ☐ Narrow_forward
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