Smartwork5 Printed Access Card for Use with Chemistry: The Science in Context 5th Edition (SmartWork Access Printed Access Card)
5th Edition
ISBN: 9780393615296
Author: Rein V. Kirss (Author), Natalie Foster (Author), Geoffrey Davies (Author) Thomas R. Gilbert (Author)
Publisher: W. W. Norton
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Chapter 11, Problem 11.78QP
Interpretation Introduction
Interpretation: The aqueous solution that has the lowest freezing point among the given solutions is to be stated.
Concept introduction: The addition of substance (solute) in a solvent is known as dissolution. After the process of dissolution the boiling point of solvent increases and the freezing point decreases. This decrease in freezing point is expressed as depression in freezing point. This depends upon the ionic and molecular property of the solute. Ionic compound after dissolution produces ions. The number of produced ions affects the value of depression in freezing point.
To determine: The aqueous solution that has the lowest freezing point among the given solutions.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 11 Solutions
Smartwork5 Printed Access Card for Use with Chemistry: The Science in Context 5th Edition (SmartWork Access Printed Access Card)
Ch. 11.1 - Prob. 1PECh. 11.2 - Prob. 2PECh. 11.2 - Prob. 3PECh. 11.2 - Prob. 4PECh. 11.3 - Prob. 5PECh. 11.4 - Prob. 6PECh. 11.4 - Prob. 7PECh. 11.5 - Prob. 8PECh. 11.5 - Prob. 9PECh. 11.5 - Prob. 10PE
Ch. 11.5 - Prob. 11PECh. 11.5 - Prob. 12PECh. 11.5 - Prob. 13PECh. 11.5 - Prob. 14PECh. 11.5 - Prob. 15PECh. 11.6 - Prob. 16PECh. 11.6 - Prob. 17PECh. 11 - Prob. 11.1VPCh. 11 - Prob. 11.2VPCh. 11 - Prob. 11.3VPCh. 11 - Prob. 11.4VPCh. 11 - Prob. 11.5VPCh. 11 - Prob. 11.6VPCh. 11 - Prob. 11.7VPCh. 11 - Prob. 11.8QPCh. 11 - Prob. 11.9QPCh. 11 - Prob. 11.10QPCh. 11 - Prob. 11.11QPCh. 11 - Prob. 11.12QPCh. 11 - Prob. 11.13QPCh. 11 - Prob. 11.14QPCh. 11 - Prob. 11.15QPCh. 11 - Prob. 11.16QPCh. 11 - Prob. 11.17QPCh. 11 - Prob. 11.18QPCh. 11 - Prob. 11.19QPCh. 11 - Prob. 11.20QPCh. 11 - Prob. 11.21QPCh. 11 - Prob. 11.22QPCh. 11 - Prob. 11.23QPCh. 11 - Prob. 11.24QPCh. 11 - Prob. 11.25QPCh. 11 - Prob. 11.26QPCh. 11 - Prob. 11.27QPCh. 11 - Prob. 11.28QPCh. 11 - Prob. 11.29QPCh. 11 - Prob. 11.30QPCh. 11 - Prob. 11.31QPCh. 11 - Prob. 11.32QPCh. 11 - Prob. 11.33QPCh. 11 - Prob. 11.34QPCh. 11 - Prob. 11.35QPCh. 11 - Prob. 11.36QPCh. 11 - Prob. 11.37QPCh. 11 - Prob. 11.38QPCh. 11 - Prob. 11.39QPCh. 11 - Prob. 11.40QPCh. 11 - Prob. 11.41QPCh. 11 - Prob. 11.42QPCh. 11 - Prob. 11.43QPCh. 11 - Prob. 11.44QPCh. 11 - Prob. 11.45QPCh. 11 - Prob. 11.46QPCh. 11 - Prob. 11.47QPCh. 11 - Prob. 11.48QPCh. 11 - Prob. 11.49QPCh. 11 - Prob. 11.50QPCh. 11 - Prob. 11.51QPCh. 11 - Prob. 11.52QPCh. 11 - Prob. 11.53QPCh. 11 - Prob. 11.54QPCh. 11 - Prob. 11.55QPCh. 11 - Prob. 11.56QPCh. 11 - Prob. 11.57QPCh. 11 - Prob. 11.58QPCh. 11 - Prob. 11.59QPCh. 11 - Prob. 11.60QPCh. 11 - Prob. 11.61QPCh. 11 - Prob. 11.62QPCh. 11 - Prob. 11.63QPCh. 11 - Prob. 11.64QPCh. 11 - Prob. 11.65QPCh. 11 - Prob. 11.66QPCh. 11 - Prob. 11.67QPCh. 11 - Prob. 11.68QPCh. 11 - Prob. 11.69QPCh. 11 - Prob. 11.70QPCh. 11 - Prob. 11.71QPCh. 11 - Prob. 11.72QPCh. 11 - Prob. 11.73QPCh. 11 - Prob. 11.74QPCh. 11 - Prob. 11.75QPCh. 11 - Prob. 11.76QPCh. 11 - Prob. 11.77QPCh. 11 - Prob. 11.78QPCh. 11 - Prob. 11.79QPCh. 11 - Prob. 11.80QPCh. 11 - Prob. 11.81QPCh. 11 - Prob. 11.82QPCh. 11 - Prob. 11.83QPCh. 11 - Prob. 11.84QPCh. 11 - Prob. 11.85QPCh. 11 - Prob. 11.86QPCh. 11 - Prob. 11.87QPCh. 11 - Prob. 11.88QPCh. 11 - Prob. 11.89QPCh. 11 - Prob. 11.90QPCh. 11 - Prob. 11.91QPCh. 11 - Prob. 11.92QPCh. 11 - Prob. 11.93QPCh. 11 - Prob. 11.94QPCh. 11 - Prob. 11.95APCh. 11 - Prob. 11.96APCh. 11 - Prob. 11.97APCh. 11 - Prob. 11.98APCh. 11 - Prob. 11.99APCh. 11 - Prob. 11.100APCh. 11 - Prob. 11.101APCh. 11 - Prob. 11.102APCh. 11 - Prob. 11.103APCh. 11 - Prob. 11.104APCh. 11 - Prob. 11.105APCh. 11 - Prob. 11.106AP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY