Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e
7th Edition
ISBN: 9780198802259
Author: ATKINS
Publisher: Oxford University Press
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Chapter 11, Problem 11.1DQ
Interpretation Introduction

Interpretation:

The form of the Beer-Lambert law has to be justified and the deviations from it has to be observed.

Concept introduction:

  • According to Beer–Lambert law, intensity of radiation absorbed at a particular frequency depends on number of species absorbed (N), molar concentration [J] and the path length, L.

  I = I010ε[J]Lwhere,ε = Molar absorption coefficient I = Intensity of incident radiationI0 = Intensity of transmitted radiation

  • Equation for transmittance, T can be given as,

   T= II0T = 10ε[J]Lwhere,I = Intensity of incident radiationI0 = Intensity of transmitted radiationN = Number of species absorbed[J] = Molar concentration L = Path length

  • Equation for absorbance, A can be given as,

  A = log TT = ε[J]Lwhere,I = Intensity of incident radiationI0 = Intensity of transmitted radiationN = Number of species absorbed[J] = Molar concentration L = Path length

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Chapter 11 Solutions

Us Solutions Manual To Accompany Elements Of Physical Chemistry 7e

Ch. 11 - Prob. 11C.3STCh. 11 - Prob. 11C.4STCh. 11 - Prob. 11C.5STCh. 11 - Prob. 11C.6STCh. 11 - Prob. 11C.7STCh. 11 - Prob. 11D.1STCh. 11 - Prob. 11D.2STCh. 11 - Prob. 11D.3STCh. 11 - Prob. 11E.1STCh. 11 - Prob. 11E.2STCh. 11 - Prob. 11E.3STCh. 11 - Prob. 11E.4STCh. 11 - Prob. 11A.1ECh. 11 - Prob. 11A.2ECh. 11 - Prob. 11A.3ECh. 11 - Prob. 11A.4ECh. 11 - Prob. 11A.5ECh. 11 - Prob. 11A.6ECh. 11 - Prob. 11A.7ECh. 11 - Prob. 11A.8ECh. 11 - Prob. 11B.1ECh. 11 - Prob. 11B.2ECh. 11 - Prob. 11B.3ECh. 11 - Prob. 11B.4ECh. 11 - Prob. 11B.5ECh. 11 - Prob. 11B.6ECh. 11 - Prob. 11B.7ECh. 11 - Prob. 11B.8ECh. 11 - Prob. 11B.9ECh. 11 - Prob. 11B.10ECh. 11 - Prob. 11B.11ECh. 11 - Prob. 11B.12ECh. 11 - Prob. 11B.13ECh. 11 - Prob. 11B.14ECh. 11 - Prob. 11B.15ECh. 11 - Prob. 11B.16ECh. 11 - Prob. 11C.1ECh. 11 - Prob. 11C.2ECh. 11 - Prob. 11C.3ECh. 11 - Prob. 11C.4ECh. 11 - Prob. 11C.5ECh. 11 - Prob. 11C.6ECh. 11 - Prob. 11C.7ECh. 11 - Prob. 11C.8ECh. 11 - Prob. 11C.9ECh. 11 - Prob. 11D.1ECh. 11 - Prob. 11D.2ECh. 11 - Prob. 11D.3ECh. 11 - Prob. 11D.4ECh. 11 - Prob. 11D.5ECh. 11 - Prob. 11D.6ECh. 11 - Prob. 11E.1ECh. 11 - Prob. 11E.2ECh. 11 - Prob. 11E.3ECh. 11 - Prob. 11.1DQCh. 11 - Prob. 11.2DQCh. 11 - Prob. 11.3DQCh. 11 - Prob. 11.4DQCh. 11 - Prob. 11.5DQCh. 11 - Prob. 11.6DQCh. 11 - Prob. 11.7DQCh. 11 - Prob. 11.8DQCh. 11 - Prob. 11.9DQCh. 11 - Prob. 11.10DQCh. 11 - Prob. 11.11DQCh. 11 - Prob. 11.12DQCh. 11 - Prob. 11.13DQCh. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8PCh. 11 - Prob. 11.9PCh. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14PCh. 11 - Prob. 11.15PCh. 11 - Prob. 11.1PRCh. 11 - Prob. 11.2PRCh. 11 - Prob. 11.3PRCh. 11 - Prob. 11.5PR
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