(a) Interpretation: The structure of alkene that would react with mCPBA to give the epoxide is to be predicted. Concept introduction: The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids. The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

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Answer 1

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Answer 2

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Expert Solution & Answer

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Answer 3

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

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Answer 4

Question

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Expert Solution & Answer

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Answer 5

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 6

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 7

Chapter 11, Problem 11.12P

Interpretation Introduction

(a)

Interpretation:

The structure of alkene that would react with mCPBA to give the epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

Concept introduction:

The laboratory preparation of epoxides involves the direct oxidation of alkenes with peroxycarboxylic acids.

The use of alkenes as a starting material for epoxide synthesis is the reason that certain epoxides are named as oxidation products of the corresponding alkenes.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 11 - Prob. 11.1P Ch. 11 - Prob. 11.2P Ch. 11 - Prob. 11.3P Ch. 11 - Prob. 11.4P Ch. 11 - Prob. 11.5P Ch. 11 - Prob. 11.6P Ch. 11 - Prob. 11.7P Ch. 11 - Prob. 11.8P Ch. 11 - Prob. 11.9P Ch. 11 - Prob. 11.10P

Solution Summary: The author explains that the structure of alkene that would react with mCPBA to give an epoxide is to be predicted.

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Chapter 11 Solutions