Structural formula for the given name has to be drawn. Concept Introduction: Nomenclature of Ether compounds: The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are, Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group. Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ ether ’. Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively. Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Question

Want to see more full solutions like this?

Answer 1

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Students have asked these similar questions

You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐

Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 CI MgCl ? Will the first product that forms in this reaction create a new CC bond? Yes No MgBr ? Will the first product that forms in this reaction create a new CC bond? Yes No G टे

Answer 2

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Answer 6

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

Answer 7

Chapter 11, Problem 11.11P

(a)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 8

(a)

Expert Solution

Explanation of Solution

IUPAC name: 2-(1-Methylethoxy)propane

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain is propane (contains three carbons) as the parent alkane; naming the –OR group as alkoxy that is ‘2-(1-methylethoxy).

Therefore, the structure obtained is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 1

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

Answer 13

(b)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 14

(b)

Expert Solution

Explanation of Solution

IUPAC name: trans-2,3-Diethyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the name‘oxirane’ contains two carbons along with one Oxygen atom in a cyclic ringalong with two ‘ethyl’ substituentsin the ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 2

Answer 15

(b)

Expert Solution

Answer 16

(b)

Expert Solution

Answer 17

Expert Solution

Answer 18

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

Answer 19

(c)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 20

(c)

Expert Solution

Explanation of Solution

IUPAC name:trans-2-Ethoxycyclopentanol

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Here, the –OH group is preferred as the first priority and the compound is ‘alcohol’.

In the given compound, the longest carbon chain contains five carbons in a cyclic ring; the parent name is CYCLOPETANE and numbering the parent chain begins with carbon attached to the –OH group located at C-1 and the substituent ‘ethoxy’ is located at C-2.

Therefore, the structure is,

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 3

Answer 21

(c)

Expert Solution

Answer 22

(c)

Expert Solution

Answer 23

Expert Solution

Answer 24

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

Answer 25

(d)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 26

(d)

Expert Solution

Explanation of Solution

IUPAC name:Ethenyloxyethene.

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain isethene (contains two carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is Ethenyl.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 4

Answer 27

(d)

Expert Solution

Answer 28

(d)

Expert Solution

Answer 29

Expert Solution

Answer 30

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

Answer 31

(e)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 32

(e)

Expert Solution

Explanation of Solution

IUPAC name:Cyclohexene oxide:

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest carbon cyclic ring contains sixcarbon atoms andone Oxygen atom is located at C-1 and 2 as three membered ring.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 5

Answer 33

(e)

Expert Solution

Answer 34

(e)

Expert Solution

Answer 35

Expert Solution

Answer 36

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

Answer 37

(f)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 38

(f)

Expert Solution

Explanation of Solution

IUPAC name:3-Cyclopropyloxy-1-propene

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon chain ispropene (contains three carbons with a double bond) as the parent alkene; naming the–OR groups as alkoxy that is 3-Cyclopropyloxy.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 6

Answer 39

(f)

Expert Solution

Answer 40

(f)

Expert Solution

Answer 41

Expert Solution

Answer 42

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

Answer 43

(g)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 44

(g)

Expert Solution

Explanation of Solution

IUPAC name:(R)-2-Methyloxirane

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Using the above principle, the longest three membered cyclic ringscontaintwo carbon atoms and one Oxygen atom and the substituent methyl group is located at C-2.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 7

Answer 45

(g)

Expert Solution

Answer 46

(g)

Expert Solution

Answer 47

Expert Solution

Answer 48

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8

Answer 49

(h)

Interpretation Introduction

Interpretation:

Structural formula for the given name has to be drawn.

Concept Introduction:

Nomenclature of Ether compounds:

The naming of theorganic compound is given by IUPAC (International Union for pure and applied chemistry). In the IUPAC names consist of certain rules for giving chemical names they are,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Common name: List the alkyl groups bonded to Oxygen in alphabetical order and adding the word ‘ether’.

Cyclic ether: The presence of Oxygen atom in a saturated ring is indicated by the prefix ox-, and ring sizes from three to six are indicated by the endings –irane, etane, olane, and –ane, respectively.

Numbering of the atoms of the ring begins with the oxygen atom. These compounds and others in which there is a heteroatom (non-carbon atom) in the ring are called heterocycles.

Answer 50

(h)

Expert Solution

Explanation of Solution

IUPAC name:1,1-Dimethyloxycyclohexane,

Ethers are named by selecting the longest carbon chain as the parent alkane and naming the –OR group bonded to it an alkoxy group.

Using the above principle, the longest carbon ringiscyclohexane (contains six carbons) as the parent alkane; naming the two–OR groups as alkoxy that bothmethoxy groups located at C-1.

OWL V2 with MindTap Reader and Student Solutions Manual eBook for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition, Chapter 11, Problem 11.11P , additional homework tip 8