Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162485
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 11, Problem 105E
Interpretation Introduction
To explain: The dependence of vaporization on surface area and nondependence of vapor pressure on surface area.
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Q3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles
Considering the following reactions:
a) Predict the products to complete the reactions.
b) Use curved electron-pushing arrows to show the mechanism for the reaction in
the forward direction. Redraw some of the compounds to explicitly illustrate all
bonds that are broken and all bonds that are formed.
c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions.
A.
S
+
AICI 3
B.
+
H₂O
3. A thermometer is placed in a test tube of chipped ice at -5.0 °C. The temperature is recorded at the
time intervals shown below until room temperature is reached. Plot the data given below on graph
paper and explain all flat, horizontal portions of the curve. Plot time on the X-axis!
Time (min)
Temperature (°C)
0
-5.0
2
-2.5
4
-1.0
6
0.0
10
0.0
15
0.0
20
0.0
25
0.0
30
1.5
35
4.0
40
8.0
45
11.5
50
15.0
55
17.5
60
19.0
65
20.0
70
20.0
75
20.0
80
20.0
Naming the Alkanes
a) Write the IUPAC nomenclature of the compound below
b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and
quaternary carbons.
c) Rank pentane, neopentane and isopentane for boiling point.
pentane:
H3C-CH2-CH2-CH2-CH3
neopentane:
CH3
H3C-Ċ-CH3
I
CH3
isopentane:
CH3
H3C-CH2-CH-CH3
Chapter 11 Solutions
Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 11 - Prob. 1SAQCh. 11 - Q2. Liquid nitrogen boils at 77 K. The image shown...Ch. 11 - Q3. Based on the expected intermolecular forces,...Ch. 11 - Q4. Which substance experiences dipole–dipole...Ch. 11 - Q5. One of these substances is a liquid at room...Ch. 11 - Prob. 6SAQCh. 11 - Q7. Determine the amount of heat (in kJ) required...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQ
Ch. 11 - Prob. 1ECh. 11 - 2. Why are intermolecular forces important?
Ch. 11 - 3. What are the main properties of liquids (in...Ch. 11 - 4. What are the main properties of solids (in...Ch. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - 13. What is hydrogen bonding? How can you predict...Ch. 11 - Prob. 14ECh. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - Prob. 18ECh. 11 - 19. Why is vaporization endothermic? Why is...Ch. 11 - 20. How is the volatility of a substance related...Ch. 11 - 21. What is the heat of vaporization for a liquid...Ch. 11 - 22. Explain the process of dynamic equilibrium....Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - 26. What is the Clausius–Clapeyron equation and...Ch. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - 31. Examine the heating curve for water in Section...Ch. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - 39. Arrange these compounds in order of increasing...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - 50. Explain why the viscosity of multigrade motor...Ch. 11 - 51. Water in a glass tube that contains grease or...Ch. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Prob. 54ECh. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - 57. The human body obtains 915 kJ of energy from a...Ch. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - Prob. 63ECh. 11 - Prob. 64ECh. 11 - Prob. 65ECh. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - 72. How much heat (in kJ) is evolved in converting...Ch. 11 - Prob. 73ECh. 11 - 74. Consider the phase diagram for iodine shown...Ch. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Prob. 78ECh. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - 82. How is the density of solid water compared to...Ch. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - 90. A sample of steam with a mass of 0.552 g and...Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - 94. A sealed flask contains 0.55 g of water at 28...Ch. 11 - Prob. 95ECh. 11 - 96. Consider a planet where the pressure of the...Ch. 11 - Prob. 97ECh. 11 - 98. Given that the heat of fusion of water is...Ch. 11 - 99. The heat of combustion of CH4 is 890.4 kJ/mol,...Ch. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - 102. Butane (C4H10) has a heat of vaporization of...Ch. 11 - Prob. 103ECh. 11 - 104. One prediction of global warming is the...Ch. 11 - Prob. 105ECh. 11 - Prob. 106ECh. 11 - Prob. 107ECh. 11 - Prob. 108ECh. 11 - Prob. 109ECh. 11 - Prob. 110ECh. 11 - Prob. 111ECh. 11 - Prob. 112ECh. 11 - Prob. 113QGWCh. 11 - Prob. 114QGWCh. 11 - Prob. 115QGWCh. 11 - Prob. 116QGWCh. 11 - 117. Students in a chemistry laboratory course are...
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