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(a)
To determine: The synthesis of the given compound from
Interpretation: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms is to be shown.
Concept introduction: Alkyl halide reacts with metals like sodium, magnesium in the presence of ether to give
Ether is used as solvent in many reactions.
(b)
To determine: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms.
Interpretation: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms is to be shown.
Concept introduction: Lithium dialkylcuprate is a reagent which is formed when two equivalents of the corresponding organolithium reagents react with cuprous iodide. It is also known as Gilman reagent.
(c)
To determine: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms.
Interpretation: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms is to be shown.
Concept introduction: Lithium dialkylcuprate is a reagent which is formed when two equivalents of the corresponding organolithium reagents react with cuprous iodide. It is also known as Gilman reagent.
(d)
To determine: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms.
Interpretation: The synthesis of the given compound from alkyl halides, vinyl halides and aryl halides containing not more than six carbon atoms is to be shown.
Concept introduction: Lithium dialkylcuprate is a reagent which is formed when two equivalents of the corresponding organolithium reagents react with cuprous iodide. It is also known as Gilman reagent.
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Chapter 10 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
- Homework: Atomic Structure This homework is due at the beginning of class next lecture period and is worth 6 points. Please place the number of protons and neutrons in the nucleus and then put the number of electrons in the correct shell. Also give the correct atomic mass. Also, state if the atom is an ion (cation or anion). H* 1. Number of protons Number of electrons Number of neutrons Atomic mass 2. 26 13AI +++ Number of protons Number of neutrons Number of electrons Atomic massarrow_forwardDon't used hand raitingarrow_forwardI need help working this problem out step by step, I was trying to use my example from the txt book but all I know how to do is set it up. I need to be shown step by step as I am a visual learner. Please help me.arrow_forward
- Don't used hand raitingarrow_forwardDon't used Ai solution and don't used hand raitingarrow_forward& Calculate the molar enthalpy of combustion (A combH) of 1.80 g of pyruvic acid (CH3COCOOH; 88.1 g mol-1) at 37 °C when they are combusted in a calorimeter at constant volume with a calorimeter constant = 1.62 kJ °C-1 and the temperature rose by 1.55 °C. Given: R = 8.314 J mol −1 °C-1 and the combustion reaction: AN C3H4O3 + 2.502(g) → 3CO2(g) + 2H2O(l)arrow_forward
- An unknown salt, AB, has the following precipitation reaction:A+(aq) + B-(aq) ⇌ AB(s) the K value for this reaction is 4.50 x10-6. Draw a model that represents what will happen when 1.00 L each of 1.00 M solution of A+(aq) and 1.00M solution of B-(aq) are combined.arrow_forward5. a) Use the rules in Example 4.4 (p. 99) and calculate sizes of octahedral and tetrahedral cavities in titanium and in zirconium. Use values for atomic radii given in Fig. 9.1 (p.291). (3 points) b) Consider the formation of carbides (MC) of these metals. Which metal is able to accommodate carbon atoms better, and which cavities (octahedral or tetrahedral) would be better suited to accommodate C atoms into metal's lattice? (4 points)arrow_forward2. Read paragraph 3.4 in your textbook ("Chiral Molecules"), and explain if Cobalt(ethylenediamine) 33+ shown in previous problem is a chiral species. If yes, draw projections of both enantiomers as mirror images, analogous to mirror projections of hands (below). Mirror (4 points)arrow_forward
- 3. Borane (BH3) belongs to D3h point group. Consider the vibrational (stretching) modes possible for B-H bonds under D3h symmetry. Using the methods we used in class, construct the reducible representation I, and break it down into irreducible representations using the character table provided. Sketch those modes, indicate whether they are IR-active. (6 points) D3h E 2C3 3C2 σh 283 30% A₁' 1 1 1 1 1 1 x² + y², z² 1 -1 1 1 -1 R₂ E' 2 0 2 0 (x, y) (x² - y², xy) " A₁" 1 1 -1 A2" 1 -1 -1 1 Z E" 2 -1 0 -2 1 0 (Ry, Ry) (xz, yz)arrow_forward1. List all the symmetry elements, and assign the compounds to proper point groups: a) HCIBrC-BrCIH Cl Br H (2 points) H Br b) Pentacarbonylmanganese(I)bromide Br OEC-Mn-CEO 00- c) Phenazine (aromatic molecule, with delocalized bonding) 1 d) Cobalt(ethylenediamine)33+ (just the cation) 3+ H₂N H₂ .NH2 (CI)3 NH2 H2 H₂N. (2 points) (2 points) (2 points)arrow_forwardHello, I desperately need help figuring out 8-14; I also wanted to see if you would mind letting me know if I picked the right degree as my melting points on the two graphs. Please and thank you in advance! All the information is provided.arrow_forward
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