ORGANIC CHEMISTRYPKGDRL+MLCRL MDL
ORGANIC CHEMISTRYPKGDRL+MLCRL MDL
3rd Edition
ISBN: 9781119416746
Author: Klein
Publisher: WILEY
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Chapter 10.6, Problem 6LTS
Interpretation Introduction

Interpretation:

The stereochemical outcome of radical bromination for the given compound should be identified.

Concept introduction:

Radical bromination: It is a type of halogenation reaction in which the bromine atom gets bonded with the alkane or alkyl substituents resulting to the product with added bromine atom via radical mechanism.

Radical reaction of Br2 is radical substitution of alkane and generates the alkyl halide and hydrogen iodide.

Stability of Radicals: Radicals are highly unstable due to its unpaired valence electron of an atom.

The increasing order of radical stability is given below

Benzylic > allylic > tertiary > secondary > primary > methyl

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Racemic mixture: A racemic mixture is simply a mixture containing an equal amount of each enantiomer.

Enantiomers: They are chiral molecules whose mirror images are not superimposable.

Diastereomers: The molecules that are not mirror images and not superimposable of each other.

Chiral carbon: Carbon is considered to be chiral if all the four substituents bonded with that carbon are different.

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Please choose the best reagents to complete the following reaction
Problem 6-17 Look at the following energy diagram: Energy Reaction progress (a) Is AG for the reaction positive or negative? Label it on the diagram. (b) How many steps are involved in the reaction? (c) How many transition states are there? Label them on the diagram. Problem 6-19 What is the difference between a transition state and an intermediate? Problem 6-21 Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and intermediate. Is AG° positive or negative? Problem 6-23 Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?
Problem 6-37 Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the following compounds. (b) (c) Problem 6-39 Show the structure of the carbocation that would result when each of the following alkenes reacts with an acid, H+. (a) (b) (c)

Chapter 10 Solutions

ORGANIC CHEMISTRYPKGDRL+MLCRL MDL

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