ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
3rd Edition
ISBN: 9781119477617
Author: Klein
Publisher: WILEY
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Chapter 10.1, Problem 5PTS
Interpretation Introduction
Interpretation:
The weakest C-H bond should be identified for the given molecule.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which weakest bond strength.
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Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 10 Solutions
ORGANIC CHEMISTRY, WITH SOL. MAN/ STUDY
Ch. 10.1 - Prob. 1CCCh. 10.1 - Prob. 1LTSCh. 10.1 - Prob. 2PTSCh. 10.1 - Prob. 3PTSCh. 10.1 - Prob. 4ATSCh. 10.1 - Prob. 2LTSCh. 10.1 - Prob. 5PTSCh. 10.1 - Prob. 6PTSCh. 10.1 - Prob. 7ATSCh. 10.2 - Prob. 3LTS
Ch. 10.2 - Prob. 8PTSCh. 10.2 - Prob. 9ATSCh. 10.3 - Prob. 4LTSCh. 10.3 - Prob. 10PTSCh. 10.3 - Prob. 11ATSCh. 10.5 - Prob. 5LTSCh. 10.5 - Prob. 12PTSCh. 10.5 - Prob. 13ATSCh. 10.6 - Prob. 6LTSCh. 10.6 - Prob. 14PTSCh. 10.6 - Prob. 15ATSCh. 10.7 - Prob. 7LTSCh. 10.7 - Prob. 16PTSCh. 10.7 - Prob. 17PTSCh. 10.7 - Prob. 18ATSCh. 10.8 - Prob. 19CCCh. 10.9 - Prob. 20CCCh. 10.10 - Prob. 8LTSCh. 10.10 - Prob. 21PTSCh. 10.10 - Prob. 22ATSCh. 10 - Prob. 23PPCh. 10 - Prob. 24PPCh. 10 - Prob. 25PPCh. 10 - Prob. 26PPCh. 10 - Prob. 27PPCh. 10 - Prob. 28PPCh. 10 - Prob. 29PPCh. 10 - Prob. 30PPCh. 10 - Prob. 31PPCh. 10 - Prob. 32PPCh. 10 - Prob. 33PPCh. 10 - Prob. 34PPCh. 10 - Prob. 35PPCh. 10 - Prob. 36PPCh. 10 - Prob. 37PPCh. 10 - Prob. 38PPCh. 10 - Prob. 39PPCh. 10 - Prob. 40PPCh. 10 - Prob. 41IPCh. 10 - Prob. 42IPCh. 10 - Prob. 43IPCh. 10 - Prob. 44IPCh. 10 - Prob. 45IPCh. 10 - Prob. 46IPCh. 10 - Prob. 47IPCh. 10 - Prob. 48IPCh. 10 - Prob. 49IPCh. 10 - Prob. 50IPCh. 10 - Prob. 51IPCh. 10 - Prob. 52IPCh. 10 - Prob. 53IPCh. 10 - Prob. 54IPCh. 10 - Prob. 55IPCh. 10 - Prob. 56IPCh. 10 - Prob. 57IPCh. 10 - Prob. 58CPCh. 10 - Prob. 59CPCh. 10 - As seen in this chapter, hydrocarbons typically do...Ch. 10 - Prob. 61CP
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