Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
3rd Edition
ISBN: 9780321806383
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 10, Problem 94E
Interpretation Introduction
Interpretation: The compound C3H4 has two double bonds. Its bonding and geometry, using a valence bond approach.
Concept Introduction:
The central carbon atom bonds with two carbon atoms. So, it undergoes sp hybridization and the structure is linear. Two p orbitals overlap with the p orbitals of the terminal carbons to form two pi bonds.
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In the electrode Pt, H2(1 atm) | H+(a=1), if the electrode balance potential is -0.118 V and the interface potential difference is +5 mV. The current voltage will be 0.005 - (-0.118) = 0.123 V ¿Correcto?
In the electrode Pt, H2(1 atm) | H+(a=1) at 298K is 0.79 mA cm-2. If the balance potential of the electrode is -0.118 V and the potential difference of the interface is +5 mV. Determine its potential.
In one electrode: Pt, H2(1 atm) | H+(a=1), the interchange current density at 298K is 0.79 mA·cm-2. If the voltage difference of the interface is +5 mV. What will be the correct intensity at pH = 2?. Maximum transfer voltage and beta = 0.5.
Chapter 10 Solutions
Masteringchemistry with Pearson Etext -- Standalone Access Card -- For Chemistry
Ch. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - Prob. 8SAQCh. 10 - Prob. 9SAQCh. 10 - Q10. Apply molecular orbital theory to predict...
Ch. 10 - Q11. Apply molecular orbital theory to determine...Ch. 10 - Q12. Which hybridization scheme occurs about...Ch. 10 - Q13. Which molecular geometry results when a...Ch. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQCh. 10 - 1. Why is molecular geometry important? Cite some...Ch. 10 - 2. According to VSEPR theory, what determines the...Ch. 10 - 3. Name and sketch the five basic electron...Ch. 10 - 4. Explain the difference between electron...Ch. 10 - 5. Give the correct electron and molecular...Ch. 10 - 6. How do you apply VSEPR theory to predict the...Ch. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - 9. In valence bond theory, what determines the...Ch. 10 - 10. In valence bond theory, the interaction energy...Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - 13. How is the number of hybrid orbitals related...Ch. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - 16. Name the hybridization scheme that corresponds...Ch. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - 19. What is a bonding molecular orbital?
Ch. 10 - 20. What is an antibonding molecular orbital?
Ch. 10 - 21. What is the role of wave interference in...Ch. 10 - Prob. 22ECh. 10 - 23. How is the number of molecular orbitals...Ch. 10 - 24. Sketch each molecular orbital.
a. σ2s
b.
c....Ch. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - 30. Write a short paragraph describing chemical...Ch. 10 - 31. A molecule with the formula AB3 has a trigonal...Ch. 10 - 32. A molecule with the formula AB3 has a trigonal...Ch. 10 - 33. For each molecular geometry, list the number...Ch. 10 - Prob. 34ECh. 10 - 35. Determine the electron geometry, molecular...Ch. 10 - Prob. 36ECh. 10 - 37. Which species has the smaller bond angle, H3O...Ch. 10 - Prob. 38ECh. 10 - 39. Determine the molecular geometry and sketch...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Determine the molecular geometry about each...Ch. 10 - 43. Each ball-and-stick model shows the electron...Ch. 10 - 44. Each ball-and-stick model shows the electron...Ch. 10 - 45. Determine the geometry about each interior...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Determine whether each molecule is polar or...Ch. 10 - Prob. 52ECh. 10 - 53. The valence electron configurations of several...Ch. 10 - 54. The valence electron configurations of several...Ch. 10 - 55. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 56ECh. 10 - 57. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 58ECh. 10 - 59. Which hybridization scheme allows the...Ch. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - 62. Write a hybridization and bonding scheme for...Ch. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - 65. Write a hybridization and bonding scheme for...Ch. 10 - Write a hybridization and bonding scheme for each...Ch. 10 - 67. Consider the structure of the amino acid...Ch. 10 - 68. Consider the structure of the amino acid...Ch. 10 - 69. Sketch the bonding molecular orbital that...Ch. 10 - Prob. 70ECh. 10 - 71. Draw an MO energy diagram and predict the bond...Ch. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - 76. Using the molecular orbital energy ordering...Ch. 10 - 77. Use molecular orbital theory to predict if...Ch. 10 - 78. Use molecular orbital theory to predict if...Ch. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - 81. Draw an MO energy diagram for CO. (Use the...Ch. 10 - Prob. 82ECh. 10 - 83. For each compound, draw the Lewis structure,...Ch. 10 - 84. For each compound, draw the Lewis structure,...Ch. 10 - 85. Amino acids are biological compounds that link...Ch. 10 - 86. The genetic code is based on four different...Ch. 10 - 87. The structure of caffeine, present in coffee...Ch. 10 - 88. The structure of acetylsalicylic acid...Ch. 10 - 89. Most vitamins can be classified as either fat...Ch. 10 - 90. Water does not easily remove grease from...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - 93. Bromine can form compounds or ions with any...Ch. 10 - 94. The compound C3H4 has two double bonds....Ch. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97ECh. 10 - 98. Indicate which orbitals overlap to form the s...Ch. 10 - 99. In VSEPR theory, which uses the Lewis model to...Ch. 10 - 100. The results of a molecular orbital...Ch. 10 - 101. The results of a molecular orbital...Ch. 10 - Prob. 102ECh. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - Prob. 105ECh. 10 - 106. Neither the VSEPR model nor the hybridization...Ch. 10 - 107. Draw the Lewis structure for acetamide...Ch. 10 - Prob. 108ECh. 10 - 109. Which statement best captures the fundamental...Ch. 10 - 110. Suppose that a molecule has four bonding...Ch. 10 - 111. How does each of the three major bonding...Ch. 10 - Prob. 112E
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- In a Pt electrode, H2(1 atm) | H+(a=1), the interchange current density of an electrode is 0.79 mA cm-2. ¿Qué corriente flow across the electrode of área 5 cm2 when the difference in potential of the interface is +5 mV?.arrow_forwardIf the current voltage is n = 0.14 V, indicate which of the 2 voltage formulas of the ley of Tafel must be applied i a a) == exp (1-B). xp[(1 - ß³): Fn Fn a b) == exp B RT RTarrow_forwardIf the current voltage is n = 0.14 V. Indicate which of the 2 formulas must be applied a) = a T = i exp[(1 - p) F Fn Fn b) i==exp B RTarrow_forward
- Topic: Photochemistry and Photophysics of Supramoleculesarrow_forwardTwo cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 Carrow_forwardWith the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.arrow_forward
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