EP BASIC CHEMISTRY-MODIFIED MASTERING
6th Edition
ISBN: 9780137452392
Author: Timberlake
Publisher: SAVVAS L
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Textbook Question
Chapter 10, Problem 83APP
Show the dipole arrow for each of the following bonds: (10.4)
a. Si and Cl
b. C and N
c. F and Cl
d. C and F
e. N and O
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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton
transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted
without ambiguity.
a.
CH3
Ph
OEt
هد
Ph
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Hint: the species on the left is an ynolate, which behaves a lot like an enolate.
b.
CH3
H3C
CH3
CH3
H3C
an unexpected product,
containing a single 9-
membered ring
the expected product,
containing two fused rings
H3C-I
(H3C)2CuLi
an enolate
b.
H3C
CH3
1.
2. H3O+
H3C
MgBr
H3C
Chapter 10 Solutions
EP BASIC CHEMISTRY-MODIFIED MASTERING
Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Determine the total number of valence electrons...Ch. 10.1 - Prob. 3PPCh. 10.1 - If the available number of valence electrons for a...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.1 - Draw the Lewis structures for each of the...Ch. 10.2 - Prob. 9PPCh. 10.2 - When does a molecular compound have resonance?
Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.2 - Draw two resonance structures for each of the...Ch. 10.3 - Prob. 13PPCh. 10.3 - Choose the shape (1 to 6) that matches each of the...Ch. 10.3 - Prob. 15PPCh. 10.3 - Prob. 16PPCh. 10.3 - Prob. 17PPCh. 10.3 - Prob. 18PPCh. 10.3 - Use VSEPR theory to predict the shape of each of...Ch. 10.3 - Prob. 20PPCh. 10.3 - Prob. 21PPCh. 10.3 - Draw the Lewis structure and predict the shape for...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Describe the trend in electronegativity as...Ch. 10.4 - Prob. 25PPCh. 10.4 - Which electronegativity difference (a, b, or c)...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Using the periodic table, arrange the atoms in...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - Predict whether the bond between each of the...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.4 - For the bond between each of the following pairs...Ch. 10.5 - Why is F2 a nonpolar molecule, but HF is a polar...Ch. 10.5 - Why is CCl4 a nonpolar molecule, but PCl3 is a...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Identify each of the following molecules as polar...Ch. 10.5 - Prob. 37PPCh. 10.5 - Prob. 38PPCh. 10.6 - Prob. 39PPCh. 10.6 - Prob. 40PPCh. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Identify the strongest intermolecular forces...Ch. 10.6 - Prob. 43PPCh. 10.6 - Prob. 44PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Prob. 47PPCh. 10.7 - Using Figure 10.6, calculate the heat change...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - Using Figure 10.6 and the specific heat of water,...Ch. 10.7 - An ice bag containing 275 g of ice at 0 °C was...Ch. 10.7 - Prob. 52PPCh. 10.7 - Prob. 53PPCh. 10.7 - In the preparation of liquid nitrogen, how many...Ch. 10.7 - Using the electronegativity values in Figure 10.2,...Ch. 10.7 - Prob. 56PPCh. 10.7 - Prob. 57PPCh. 10.7 - a. Draw two resonance structures for bicarbonate...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - State the number of valence electrons, bonding...Ch. 10 - Prob. 61UTCCh. 10 - Prob. 62UTCCh. 10 - Consider the following bonds: Ca and O, C and O, K...Ch. 10 - Consider the following bonds: F and Cl, Cl and Cl,...Ch. 10 - Identify the major intermolecular forces between...Ch. 10 - Prob. 66UTCCh. 10 - Prob. 67UTCCh. 10 - Prob. 68UTCCh. 10 - Prob. 69UTCCh. 10 - Prob. 70UTCCh. 10 - Prob. 71UTCCh. 10 - Prob. 72UTCCh. 10 - Prob. 73APPCh. 10 - Determine the total number of valence electrons in...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw the Lewis structures for each of the...Ch. 10 - Draw resonance structures for each of the...Ch. 10 - Prob. 78APPCh. 10 - Use the periodic table to arrange the following...Ch. 10 - Use the periodic table to arrange the following...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Select the more polar bond in each of the...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Show the dipole arrow for each of the following...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Calculate the electronegativity difference and...Ch. 10 - Prob. 87APPCh. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - For each of the following, draw the Lewis...Ch. 10 - Prob. 91APPCh. 10 - Predict the shape and polarity of each of the...Ch. 10 - Prob. 93APPCh. 10 - Prob. 94APPCh. 10 - Prob. 95APPCh. 10 - Indicate the major type of intermolecular...Ch. 10 - When it rains or snows, the air temperature seems...Ch. 10 - Prob. 98APPCh. 10 - Using Figure 10.6, calculate the grams of ice that...Ch. 10 - Using Figure 10.6, calculate the grams of ethanol...Ch. 10 - Prob. 101APPCh. 10 - Using Figure 10.6, calculate the grams of benzene...Ch. 10 - Prob. 103CPCh. 10 - Prob. 104CPCh. 10 - Prob. 105CPCh. 10 - Prob. 106CPCh. 10 - Prob. 107CPCh. 10 - The melting point of benzene is 5.5 °C, and its...Ch. 10 - A 45.0-g piece of ice at 0.0 °C is added to a...Ch. 10 - An ice cube at 0 °C with a mass of 115 g is added...Ch. 10 - Prob. 111CPCh. 10 - Prob. 112CPCh. 10 - Prob. 13CICh. 10 - Prob. 14CICh. 10 - Prob. 15CICh. 10 - Ethanol, C2H6O , is obtained from renewable crops...Ch. 10 - Chloral hydrate, a sedative and hypnotic, was the...Ch. 10 - Ethylene glycol, C2H6O2 , used as a coolant and...Ch. 10 - Prob. 19CICh. 10 - Prob. 20CI
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