Laboratory Experiments for Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134566207
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Chapter 10, Problem 74E
(a)
Interpretation Introduction
To determine: The partial pressure of
(b)
Interpretation Introduction
To determine: The partial pressure of
(c)
Interpretation Introduction
To determine: The total pressure of the mixture present in the
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 10 Solutions
Laboratory Experiments for Chemistry: The Central Science (14th Edition)
Ch. 10.2 - Prob. 10.1.1PECh. 10.2 -
Gallium melts just above room temperature...Ch. 10.2 - Prob. 10.2.1PECh. 10.2 - Prob. 10.2.2PECh. 10.3 - Prob. 10.3.1PECh. 10.3 - Prob. 10.3.2PECh. 10.4 - Prob. 10.4.1PECh. 10.4 - Prob. 10.4.2PECh. 10.4 - Prob. 10.5.1PECh. 10.4 - Prob. 10.5.2PE
Ch. 10.4 - Prob. 10.6.1PECh. 10.4 - Prob. 10.6.2PECh. 10.5 - Prob. 10.7.1PECh. 10.5 - Prob. 10.7.2PECh. 10.5 - Prob. 10.8.1PECh. 10.5 - Prob. 10.8.2PECh. 10.5 - Prob. 10.9.1PECh. 10.5 - Prob. 10.9.2PECh. 10.6 - Prob. 10.10.1PECh. 10.6 - Prob. 10.10.2PECh. 10.6 - Prob. 10.11.1PECh. 10.6 - Prob. 10.11.2PECh. 10.7 - Prob. 10.12.1PECh. 10.7 - Prob. 10.12.2PECh. 10.8 - Fill in the blanks for the following statement:...Ch. 10.8 - Prob. 10.13.2PECh. 10.8 - Prob. 10.14.1PECh. 10.8 - Prob. 10.14.2PECh. 10.9 - Calculate the pressure of a 2975-mol sample of N2...Ch. 10.9 - Prob. 10.15.2PECh. 10 - Prob. 1DECh. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Consider the sample of gas depicted here_ What...Ch. 10 - Imagine that the reaction 2CO(g)+O2(g)2CO(g)...Ch. 10 - Suppose you have a fixed amount of an ideal gas at...Ch. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10ECh. 10 -
10.11 A thin glass tube 1 m long is filled with...Ch. 10 -
10.12 The graph below shows the change in...Ch. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - a. The compound 1-iodododecane is a nonvolatile...Ch. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Prob. 23ECh. 10 - Prob. 24ECh. 10 - You have a gas at 25C confined to a cylinder with...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Nitrogen and hydrogen gases react to form ammonia...Ch. 10 -
10.29
a. What conditions are represented by the...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Prob. 36ECh. 10 - Calculate the number of molecules in deep breath...Ch. 10 - If the pressure exerted by ozone, O3, in the...Ch. 10 - A scuba diver’s tank contain 0.29 kg of O2...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Chlorine is widely used to purify municipal water...Ch. 10 - Many gases are shipped in high-pressure...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Rank the following gases from least to denser at...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Magnesium can be used as a ‘getter” in evacuated...Ch. 10 - Prob. 56ECh. 10 - The metabolic oxidation of glucose, C6H12O6, in...Ch. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Consider the apparatus shown in the following...Ch. 10 - Prob. 62ECh. 10 - A mixture containing 0.75 mol He(g), 0.330 mol...Ch. 10 - A deep-sea diver uses a gas cylinder with a volume...Ch. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Indicate which of the following statement...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Suppose you have two 1-L flasks, one containing N2...Ch. 10 - Prob. 81ECh. 10 -
10.8
Place the following gases in order of...Ch. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97AECh. 10 - A gas bubble with a volume of 1.0 mm3 originates...Ch. 10 - A 15.0-L tank is filled with helium gas at a...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - Prob. 103AECh. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Prob. 109AECh. 10 - The density of gas of unknown molar mass was...Ch. 10 - A glass vessel fitted with a stopcock valve has a...Ch. 10 - Prob. 112AECh. 10 -
10.113 consider the following gases. All at STP:...Ch. 10 - Prob. 114AECh. 10 - Prob. 115AECh. 10 - Prob. 116AECh. 10 - Prob. 117AECh. 10 - Prob. 118IECh. 10 - Prob. 119IECh. 10 - Prob. 120IECh. 10 -
10.121 A 4.00-g sample of a mixture of CaO and...Ch. 10 - Prob. 122IECh. 10 - Prob. 123IECh. 10 - Chlorine dioxide gas (CIO2) is used as a...Ch. 10 - Natural gas is very abundant in many Middle...Ch. 10 - Prob. 126IECh. 10 - Prob. 127IE
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- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forward
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