The compounds C and D should be identified. Concept introduction: Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer. Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer) . Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination. Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position. Radical Bromination: 2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

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Answer 1

Question

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 2

Question

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

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Answer 3

Question

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

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Answer 4

Question

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

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Answer 5

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Answer 6

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

Answer 7

Chapter 10, Problem 37PP

a.

Interpretation Introduction

Interpretation:

The compounds C and D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Radical Bromination:

2-methyl propane undergoes radical bromination which yields the 2-bromo-2-methylpropane.because bromination will occur where the tertiary radical is present. (Bromination reactions are more selective reaction). Bromination will occur on tertiary radical than the secondary than primary radical, tertiary radical is more stable radical than the other radicals.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The compound D should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The compound C should be identified.

Concept introduction:

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Hofmann's Rule: It is elimination reaction in which the formation of alkene from rather most unhindered (least substituted) β-hydrogen elimination.

Saytzeff's Rule: It is elimination reaction in which the formation of olefin on most hindered or highly substituted position.

Answer 12

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Answer 15

Ch. 10.1 - Prob. 1CC Ch. 10.1 - Prob. 1LTS Ch. 10.1 - Prob. 2PTS Ch. 10.1 - Prob. 3PTS Ch. 10.1 - Prob. 4ATS Ch. 10.1 - Prob. 2LTS Ch. 10.1 - Prob. 5PTS Ch. 10.1 - Prob. 6PTS Ch. 10.1 - Prob. 7ATS Ch. 10.2 - Prob. 3LTS

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