Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780133890686
Author: Tro
Publisher: PEARSON
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Chapter 10, Problem 35E
Interpretation Introduction
Interpretation: The electron geometry, molecular geometry, and idealized bond angle for each molecule. Also, deviations from the idealized bond angle.
Concept Introduction:
A bond angle is the angle between two bondsoriginating from the same atom in a covalent species.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ
Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions
about this system:
?
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
0.035 atm
✓
G
00.
18
Ar
Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area.
HO-
HO-
-0
OH
OH
HO
NG
HO-
HO-
OH
OH
OH
OH
NG
OH
€
+
Suppose the molecule in the drawing area below were reacted with H₂ over a platinum catalyst. Edit the molecule to show what would happen to it. That is, turn
it into the product of the reaction.
Also, write the name of the product molecule under the drawing area.
Name: ☐
H
C=0
X
H-
OH
HO-
H
HO-
-H
CH₂OH
×
Chapter 10 Solutions
Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach
Ch. 10 - Prob. 1SAQCh. 10 - Prob. 2SAQCh. 10 - Prob. 3SAQCh. 10 - Prob. 4SAQCh. 10 - Prob. 5SAQCh. 10 - Prob. 6SAQCh. 10 - Prob. 7SAQCh. 10 - Prob. 8SAQCh. 10 - Prob. 9SAQCh. 10 - Q10. Apply molecular orbital theory to predict...
Ch. 10 - Q11. Apply molecular orbital theory to determine...Ch. 10 - Q12. Which hybridization scheme occurs about...Ch. 10 - Q13. Which molecular geometry results when a...Ch. 10 - Prob. 14SAQCh. 10 - Prob. 15SAQCh. 10 - 1. Why is molecular geometry important? Cite some...Ch. 10 - 2. According to VSEPR theory, what determines the...Ch. 10 - 3. Name and sketch the five basic electron...Ch. 10 - 4. Explain the difference between electron...Ch. 10 - 5. Give the correct electron and molecular...Ch. 10 - 6. How do you apply VSEPR theory to predict the...Ch. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - 9. In valence bond theory, what determines the...Ch. 10 - 10. In valence bond theory, the interaction energy...Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - 13. How is the number of hybrid orbitals related...Ch. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - 16. Name the hybridization scheme that corresponds...Ch. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - 19. What is a bonding molecular orbital?
Ch. 10 - 20. What is an antibonding molecular orbital?
Ch. 10 - 21. What is the role of wave interference in...Ch. 10 - Prob. 22ECh. 10 - 23. How is the number of molecular orbitals...Ch. 10 - 24. Sketch each molecular orbital.
a. σ2s
b.
c....Ch. 10 - Prob. 25ECh. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - Prob. 29ECh. 10 - 30. Write a short paragraph describing chemical...Ch. 10 - 31. A molecule with the formula AB3 has a trigonal...Ch. 10 - 32. A molecule with the formula AB3 has a trigonal...Ch. 10 - 33. For each molecular geometry, list the number...Ch. 10 - Prob. 34ECh. 10 - 35. Determine the electron geometry, molecular...Ch. 10 - Prob. 36ECh. 10 - 37. Which species has the smaller bond angle, H3O...Ch. 10 - Prob. 38ECh. 10 - 39. Determine the molecular geometry and sketch...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Determine the molecular geometry about each...Ch. 10 - 43. Each ball-and-stick model shows the electron...Ch. 10 - 44. Each ball-and-stick model shows the electron...Ch. 10 - 45. Determine the geometry about each interior...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Determine whether each molecule is polar or...Ch. 10 - Prob. 52ECh. 10 - 53. The valence electron configurations of several...Ch. 10 - 54. The valence electron configurations of several...Ch. 10 - 55. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 56ECh. 10 - 57. Write orbital diagrams (boxes with arrows in...Ch. 10 - Prob. 58ECh. 10 - 59. Which hybridization scheme allows the...Ch. 10 - Prob. 60ECh. 10 - Prob. 61ECh. 10 - 62. Write a hybridization and bonding scheme for...Ch. 10 - Prob. 63ECh. 10 - Prob. 64ECh. 10 - 65. Write a hybridization and bonding scheme for...Ch. 10 - Write a hybridization and bonding scheme for each...Ch. 10 - 67. Consider the structure of the amino acid...Ch. 10 - 68. Consider the structure of the amino acid...Ch. 10 - 69. Sketch the bonding molecular orbital that...Ch. 10 - Prob. 70ECh. 10 - 71. Draw an MO energy diagram and predict the bond...Ch. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - 76. Using the molecular orbital energy ordering...Ch. 10 - 77. Use molecular orbital theory to predict if...Ch. 10 - 78. Use molecular orbital theory to predict if...Ch. 10 - Prob. 79ECh. 10 - Prob. 80ECh. 10 - 81. Draw an MO energy diagram for CO. (Use the...Ch. 10 - Prob. 82ECh. 10 - 83. For each compound, draw the Lewis structure,...Ch. 10 - 84. For each compound, draw the Lewis structure,...Ch. 10 - 85. Amino acids are biological compounds that link...Ch. 10 - 86. The genetic code is based on four different...Ch. 10 - 87. The structure of caffeine, present in coffee...Ch. 10 - 88. The structure of acetylsalicylic acid...Ch. 10 - 89. Most vitamins can be classified as either fat...Ch. 10 - 90. Water does not easily remove grease from...Ch. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - 93. Bromine can form compounds or ions with any...Ch. 10 - 94. The compound C3H4 has two double bonds....Ch. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97ECh. 10 - 98. Indicate which orbitals overlap to form the s...Ch. 10 - 99. In VSEPR theory, which uses the Lewis model to...Ch. 10 - 100. The results of a molecular orbital...Ch. 10 - 101. The results of a molecular orbital...Ch. 10 - Prob. 102ECh. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - Prob. 105ECh. 10 - 106. Neither the VSEPR model nor the hybridization...Ch. 10 - 107. Draw the Lewis structure for acetamide...Ch. 10 - Prob. 108ECh. 10 - 109. Which statement best captures the fundamental...Ch. 10 - 110. Suppose that a molecule has four bonding...Ch. 10 - 111. How does each of the three major bonding...Ch. 10 - Prob. 112E
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