EBK PHYSICAL UNIVERSE
15th Edition
ISBN: 9780100255036
Author: KRAUSKOPF
Publisher: YUZU
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Chapter 10, Problem 30E
To determine
To remove an electron from the valence shell is relatively easy or hard for sulfur.
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6. We used the constant volume heat capacity, Cv, when we talked about
thermodynamic cycles. It acts as a proportionality constant between energy and
temperature: dU = C₁dT.
You can also define a heat capacity for constant pressure processes, Cp. You can think
of enthalpy playing a similar role to energy, but for constant pressure processes
δαρ
C = (37) - Sup
Ср
ат
P
=
ат
Starting from the definition of enthalpy, H = U + PV, find the relationship between Cy
and Cp for an ideal gas.
Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt
= 41°C. Reversible melting experiments indicate that
at Tm
AHm=37.7 kJ mol-1. Calculate:
A. The entropy of melting, ASm-
B. The Gibbs free energy of melting, AGm-
C. Does the membrane become more or less ordered upon melting?
D. There are 32 rotatable CH2
CH2 bonds in each molecule that can rotate more freely if the
membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if
you go over a large temperature range. The heat capacity for liquid n-butane can be
fit to the equation
Cp(T) = a + bT
where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K)
to its boiling point (T₁ = 270 K).
A. Compute AH for heating butane from 170 K to 270 K.
B. Compute AS for the same temperature range.
Chapter 10 Solutions
EBK PHYSICAL UNIVERSE
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